化工学报 ›› 2021, Vol. 72 ›› Issue (8): 4009-4018.DOI: 10.11949/0438-1157.20201905

• 热力学 • 上一篇    下一篇

甲烷二元体系的固液相平衡预测

王宪1,2(),赵延兴1(),董学强1,陈晓刚3,公茂琼1   

  1. 1.中国科学院理化技术研究所低温工程学重点实验室,北京 100190
    2.中国科学院大学,北京 100049
    3.国网浙江省电力有限公司,浙江 杭州 310007
  • 收稿日期:2020-12-24 修回日期:2021-05-27 出版日期:2021-08-05 发布日期:2021-08-05
  • 通讯作者: 赵延兴
  • 作者简介:王宪(1994—),男,博士研究生,wangxian1033@126.com
  • 基金资助:
    国家重点研发计划项目(2018YFB0904400);国家自然科学基金项目(51876215);国家电网公司科技项目(52110418003H)

Prediction of solid-liquid equilibrium of binary mixtures containing methane

Xian WANG1,2(),Yanxing ZHAO1(),Xueqiang DONG1,Xiaogang CHEN3,Maoqiong GONG1   

  1. 1.State Key Laboratory of Technologies in Space Cryogenic Propellants, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    2.University of Chinese Academy of Sciences, Beijing 100049, China
    3.State Grid Zhejiang Electric Power Co. , Ltd. , Hangzhou 310007, Zhejiang, China
  • Received:2020-12-24 Revised:2021-05-27 Online:2021-08-05 Published:2021-08-05
  • Contact: Yanxing ZHAO

摘要:

超导能源管道是以液化天然气(LNG)冷却超导电缆,实现两种能源同时输送的前瞻性能源输送技术。超导能源管道的经济运行温度一般在77~100 K,而在此温区LNG有凝固风险,因此必须研究LNG主要成分的固液相平衡特性。为此,针对甲烷+乙烯、甲烷+乙烷、甲烷+丙烷、甲烷+正丁烷、甲烷+正戊烷5种二元混合物,借助以PR-vdW为代表的状态方程法,以NRTL、WILSON、UNIQUAC等模型为代表的活度系数法,基于所研究体系的二元汽液相平衡数据,回归二元相互作用参数,预测其二元固液相平衡,预测结果与文献数据进行了比较。结果表明,PR-vdW方程对5种甲烷二元体系的固液平衡预测结果最好。进而研究了PR-vdW方程中二元相互作用参数对甲烷二元体系汽液平衡及固液平衡计算结果的影响,分析了模型对温度的依赖关系。

关键词: 超导能源管道, 天然气, 汽液相平衡, 固液相平衡, Peng-Robinson方程

Abstract:

Superconducting energy pipeline is a forward-looking energy transmission technology that cools superconducting cables with liquefied natural gas (LNG) and realizes the simultaneous transmission of two energy sources. The economic operating temperature of superconducting energy pipelines is generally 77—100 K, and LNG has a risk of solidification in this temperature range, so it is necessary to study the solid-liquid equilibrium characteristics of the main components of LNG. This article focuses on five binary mixtures of methane+ethylene, methane+ethane, methane+propane, methane+n-butane, and methane+n-pentane, using the equation of state represented by the Peng–Robinson (PR) equation of state with the simple van der Waals (vdW) mixing rule. The activity coefficient method represented by models such as NRTL (non-random two liquids), WILSON and UNIQUAC (universal quasi–chemical). Based on the binary data of vapor-liquid equilibrium for the studied system and the regressed binary interaction parameters, the solid-liquid equilibrium of five binary mixtures was predicted, and the results were compared with the literature data. The results show that the PR-vdW equation has the best prediction results for the solid-liquid equilibrium of the five binary mixtures containing methane. Furthermore, the effects of the binary interaction parameters in the PR-vdW equation on the calculation results of the vapor or solid-liquid equilibria of the five binary mixtures were studied, and the dependence of the model on temperature was analyzed.

Key words: superconducting energy pipeline, natural gas, vapor-liquid equilibrium, solid-liquid equilibrium, Peng-Robinson equation

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