化工学报 ›› 2021, Vol. 72 ›› Issue (9): 4445-4457.DOI: 10.11949/0438-1157.20210090

• 综述与专论 • 上一篇    下一篇

木质素碳纳米材料制备及在催化中的应用研究进展

王欢1(),符方宝1,李琼1,席跃宾2(),杨东杰1()   

  1. 1.华南理工大学化学与化工学院,广东 广州 510640
    2.齐鲁工业大学(山东省科学院)制浆造纸科学与技术教育部 重点实验室,生物基材料与绿色造纸国家重点实验室,山东 济南 250353
  • 收稿日期:2021-01-13 修回日期:2021-03-30 出版日期:2021-09-05 发布日期:2021-09-05
  • 通讯作者: 席跃宾,杨东杰
  • 作者简介:王欢(1988—),男,博士,助理研究员,cewanghuan@scut.edu.cn
  • 基金资助:
    国家重点研发计划项目(2018YFB1501503);国家自然科学基金项目(21878114);广东省自然科学基金项目(2018B030311052);中国博士后科学基金项目(2019M652901);制浆造纸科学与技术教育部重点实验室开放基金项目(KF201902)

Research progress on the preparation of lignin-derived carbon materials and their application in catalysis

Huan WANG1(),Fangbao FU1,Qiong LI1,Yuebin XI2(),Dongjie YANG1()   

  1. 1.School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
    2.Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, Shandong, China
  • Received:2021-01-13 Revised:2021-03-30 Online:2021-09-05 Published:2021-09-05
  • Contact: Yuebin XI,Dongjie YANG

摘要:

木质素是自然界储量丰富的可再生资源,含碳量高且具有三维网状结构和大量共轭结构。碳材料是一类具有极大应用价值的催化材料,特别是在电催化、热催化和光催化领域。以木质素为原料制备高活性的木质素碳基催化剂是实现木质素高附加值利用有效的途径之一。木质素碳催化材料研究涉及化学、化工和物理等多个学科领域,制备性能优异和稳定性良好的木质素碳基催化剂仍充满挑战。本文主要总结了木质素碳材料的制备研究进展,以及介绍了木质素碳材料在光催化、热催化和电催化等领域的应用研究现状。此外,还分析了当前木质素碳基催化材料存在的问题,并展望了未来的发展趋势和重点研究方向。

关键词: 生物质, 木质素碳材料, 制备, 催化剂, 催化剂载体

Abstract:

Lignin is a renewable resource with abundant natural reserves, high carbon content, three-dimensional network structure, and a large number of conjugate structures. Carbon materials are a kind of catalyst materials with great application value, especially in the fields of electrocatalysis, thermal catalysis and photocatalysis. The preparation of lignin-derived carbon catalysts with high catalytic activity through precise control of their microstructure characteristics is one of the most effective ways to realize the ultra-high value-added utilization of lignin. The research of lignin-derived carbon catalysts is an interdisciplinary frontier subject involving chemistry, chemical engineering, physics and other disciplines. The controllable preparation of lignin-based carbon catalysts with excellent performance and good stability is still a challenging subject. This article mainly summarizes the recent research of lignin-derived carbon materials, and introduces the application in photocatalysis, thermal catalysis, and electrocatalysis. In addition, the current problems of lignin carbon-based catalytic materials are analyzed, and future development trends and key research directions are prospected.

Key words: biomass, lignin-derived carbon materials, preparation, catalyst, catalyst support

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