化工学报 ›› 2022, Vol. 73 ›› Issue (7): 2895-2901.DOI: 10.11949/0438-1157.20211547

• 流体力学与传递现象 • 上一篇    下一篇

微纳多孔结构中稀薄气体流动渗透率的解析型预测模型

杨光1(),程鑫1,王峥1,王晔1,张良俊2,吴静怡1   

  1. 1.上海交通大学机械与动力工程学院,上海 200240
    2.上海宇航系统工程研究所,上海 201108
  • 收稿日期:2021-11-02 修回日期:2022-04-19 出版日期:2022-07-05 发布日期:2022-08-01
  • 通讯作者: 杨光
  • 作者简介:杨光(1988—),男,博士,副教授,y_g@sjtu.edu.cn
  • 基金资助:
    国家自然科学基金项目(51906142);上海市科学技术委员会项目(18DZ2272200)

Analytical prediction model of permeability for rarefied gas flow in porous structures with micro or nanopores

Guang YANG1(),Xin CHENG1,Zheng WANG1,Ye WANG1,Liangjun ZHANG2,Jingyi WU1   

  1. 1.School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
    2.Shanghai Aerospace System Engineering Institute, Shanghai 201108, China
  • Received:2021-11-02 Revised:2022-04-19 Online:2022-07-05 Published:2022-08-01
  • Contact: Guang YANG

摘要:

针对多孔结构内气体表观渗透率受稀薄效应的影响而显著高于其固有渗透率的现象,从孔隙尺度流线的几何拓扑特性出发,提出了利用固有渗透率、孔隙率、弯曲度和收缩-扩张因子来表示多孔结构的有效孔隙尺寸的方法,并将该有效孔隙尺寸与经典的稀薄气体管道流动模型相结合,理论推导出一种新的多孔结构稀薄气体渗透率模型。利用该模型,可以在孔隙几何结构和物性状态已知的条件下对气体的表观渗透率进行预测。随后,通过高精度的直接模拟Monte Carlo方法(DSMC)对提出模型的准确性进行验证。通过对Knudsen数在0.01~10范围、孔隙率在0.17~0.90范围、不同气体工质以及多种有序性孔隙形式下的气体流动过程进行数值模拟表明,所提出的理论模型与模拟数据的平均偏差小于10%。

关键词: 多孔结构, 稀薄气体, 渗透率, 有效孔隙尺寸, 直接模拟Monte Carlo方法

Abstract:

The transport mechanism of gas in porous structures is widely used in aerospace, energy, and chemical industries. In low-pressure environments or micro/nano-scale pores, there is a phenomenon that the apparent gas permeability in porous structures is significantly higher than its intrinsic permeability due to the rarefaction effect. The existing models of the apparent permeability are mostly empirical formulas obtained by fitting experimental or simulated data, which are not universal. Based on the geometric topology characteristics of pore-scale streamlines, a method using intrinsic permeability, porosity, tortuosity and shrinkage is proposed. Subsequently, a novel model of the rarefied gas permeability was theoretically derived by combining the effective pore size with the existing model of rarefied gas flowing in pipeline. Using this model, the apparent gas permeability could be predicted under the condition that the pore geometry and physical properties are known. Furthermore, the accuracy of the proposed model was verified by the direct simulation Monte Carlo (DSMC) method. The numerical simulation of the gas flow process under the Knudsen number in the range of 0.01—10, the porosity in the range of 0.17—0.90, different gas working fluids and various ordered pore forms shows the average deviation of the proposed theoretical model from the simulated data is less than 10%.

Key words: porous structure, rarefied gas, permeability, effective pore size, DSMC

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