化工学报 ›› 2022, Vol. 73 ›› Issue (9): 4187-4193.DOI: 10.11949/0438-1157.20220484

• 材料化学工程与纳米技术 • 上一篇    下一篇

二硫代水杨酸衍生物对光固化材料性能的影响

鞠小兵1(), 李雪纯1, 孙芳1,2()   

  1. 1.北京化工大学化学学院,北京 100029
    2.北京化工大学安庆研究院,安徽 安庆 246000
  • 收稿日期:2022-04-05 修回日期:2022-05-27 出版日期:2022-09-05 发布日期:2022-10-09
  • 通讯作者: 孙芳
  • 作者简介:鞠小兵(1995—),男,硕士研究生,xiaobingju@163.com
  • 基金资助:
    国家自然科学基金项目(52073018)

Effect on dithiosalicylic acid derivative on properties of photocuring materials

Xiaobing JU1(), Xuechun LI1, Fang SUN1,2()   

  1. 1.College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
    2.Anqing Research Institute, Beijing University of Chemical Technology, Anqing 246000, Anhui, China
  • Received:2022-04-05 Revised:2022-05-27 Online:2022-09-05 Published:2022-10-09
  • Contact: Fang SUN

摘要:

设计、合成了一种二硫代水杨酸衍生物(MAPBS),详细研究了MAPBS对丙烯酸酯类单体光聚合动力学及其聚合物膜体积收缩、耐热性能及硬度的影响。研究结果表明,在365 nm LED光源照射下,MAPBS能够引发甲基丙烯酸酯类单体聚合和降低聚合物膜体积收缩。随着MAPBS含量的增加,光聚合体系的双键转化率和聚合速率随之增加,分别达到64.9%和1.19%/s,而体积收缩呈现先降低再增加的趋势,聚合物膜热稳定性略微降低,硬度略有增加。MAPBS兼具引发和降低体积收缩的双重功能,在LED光聚合体系表现出一定的应用潜力。

关键词: 光化学, 合成, 聚合, LED 光聚合, 体积收缩, 二硫化合物

Abstract:

A dithiosalicylic acid derivative (MAPBS) was designed and synthesized. The effects of MAPBS on the photopolymerization kinetics of methacrylate monomers, and the volume shrinkage, thermostability and hardness of polymer films were investigated in detail. The results show that MAPBS can initiate the polymerization of methacrylate monomers and reduce the volume shrinkage of polymer films under 365 nm LED irradiation. With the increase of MAPBS content, the double bond conversion and photopolymerization rate are increased to 64.9% and 1.19%/s, respectively, while the volume shrinkage is decreased initially and followed by an increase. Furthermore, the thermostability of polymer films is slightly reduced, while their hardness is increased a little. MAPBS has the dual functions of initiating polymerization and reducing volume shrinkage, and certain application potential in LED photopolymerization system.

Key words: photochemistry, synthesis, polymerization, LED photopolymerization, volume shrinkage, disulfide

中图分类号: