CIESC Journal ›› 2018, Vol. 69 ›› Issue (6): 2782-2789.DOI: 10.11949/j.issn.0438-1157.20171327

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Effects of biochar-based catalyst preparation on oxidation degradation of Ni-EDTA

WANG Hongjie1,2, GAO Yaguang1, ZHAO Zilong1, CHEN Guanhan1, DONG Wenyi1,2   

  1. 1. School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen Graduate School, Shenzhen 518055, Guangdong, China;
    2. Shenzhen Key Laboratory of Water Resource Application and Environmental Pollution Control, Shenzhen 518055, Guangdong, China
  • Received:2017-09-29 Revised:2017-11-15 Online:2018-06-05 Published:2018-06-05
  • Supported by:

    supported by the Urban Water Pollution Control and Management Generic Technology Integrated Program (2012ZX07206-002), Knowledge Innovation Program of Shenzhen Basic Research Project (JCYJ20160318093930497) and Guangdong Natural Science Foundation (2017A030310670).

生物炭基催化剂制备对其催化降解Ni-EDTA性能影响

王宏杰1,2, 高亚光1, 赵子龙1, 陈冠翰1, 董文艺1,2   

  1. 1. 哈尔滨工业大学深圳研究生院, 广东 深圳 518055;
    2. 深圳市水资源利用与环境污染控制重点实验室, 广东 深圳 518055
  • 通讯作者: 赵子龙
  • 基金资助:

    国家水体污染控制与治理科技重大专项(2012ZX07206-002);深圳市科技计划项目(JCYJ20160318093930497);广东省自然科学基金项目(2017A030310670)。

Abstract:

Novel biochar-based catalysts using the lignin, collagen, and copper nitrate as raw materials were prepared by the co-pyrolysis method. Through the characterization by various techniques, the effects of preparation methods and process parameters on treatment of Ni-EDTA by catalytic wet hydrogen peroxide oxidation (CWPO) were investigated, and the deactivation mechanism of biochar-based catalyst was discussed. The results showed that the co-pyrolysis method was more favorable to the improvement of catalytic performance, homogeneous distribution and dissolution control of active component, exhibiting an increase of 13.05% and 16.63% in Ni and TOC removal efficiencies and a decline of 93.54% Cu leaching, respectively. Removal efficiencies of Ni (65.41%) and TOC (34.85%) were achieved after 60 min treatment at optimum conditions (i.e. calcination temperature of 800℃, Cu dosage of 10%, mass ratio of collagen to lignin of 1:3) and the corresponding leaching content of Cu was merely 1.7 mg·L-1. Besides, the deactivation mechanism of the biochar-based catalysts herein involved the formation of carboxylic acid intermediates, leaching and valence state transformation of copper.

Key words: lignin, collagen, catalyst, preparation, Ni-EDTA, deactivation

摘要:

以胶原蛋白、木质素和硝酸铜为原料,采用共混热解法制备新型生物炭基铜系催化剂,通过多种表征手段考察制备方法和参数对催化湿式过氧化氢氧化(CWPO)处理Ni-EDTA模拟废液效果的影响,并阐述氧化降解过程中生物炭基铜系催化剂的失活机制。结果表明,相比溶液浸渍法,共混热解法有利于提高催化剂的催化活性,控制活性组分的均质分布和溶出释放,表现为Ni和TOC去除率分别增加13.05%和16.63%,Cu2+溶出量降低93.54%;在焙烧温度为800℃,Cu掺量为10%,胶原蛋白与木质素质量比例为1:3条件下,1000 mg·L-1 Ni-EDTA模拟废液经60 min催化氧化后Ni和TOC去除率分别达到65.41%和34.85%,Cu2+溶出量仅为1.7 mg·L-1。氧化降解过程中羧酸类中间降解产物的形成、活性组分反应性溶出和价态转变是致使催化剂失活的主要原因。

关键词: 木质素, 胶原蛋白, 催化剂, 制备, Ni-EDTA, 失活

CLC Number: