金属纳米颗粒辅助木质纤维素暗发酵生物制氢的研究进展

童海航,石德智,刘嘉宇,蔡桦伊,罗丹,陈飞

Research progress on dark fermentative bio-hydrogen production from lignocellulose assisted by metal nanoparticles

Haihang TONG,Dezhi SHI,Jiayu LIU,Huayi CAI,Dan LUO,Fei CHEN

表2 不同类型金属纳米材料在暗发酵生物制氢中的应用

Table 2 Application of different MNPs in dark fermentative hydrogen production

序号 微生物种类 基质 条件参数 纳米材料 H2产量提高效果① 1 Enterobacter straw pH 7,37℃ Fe0NPs 提高73.1%[91] 2 Enterobacter cloacae DH-89 glucose pH 7,37℃ FeNPs 提高230%[94] 3 Clostridium pasteurianum glucose 35℃ Fe2O3 NPs 提高52.5%[80] 4 Clostridium butyricum sucrose pH 7,35℃ α-Fe2O3 NPs 提高32.64%[60] 5 Enterobacter aerogenes glucose pH 6.0,37℃ γ- Fe2O3 NPs 提高17%[24] 6 mixed culture bacteria inorganic salt pH 6,37℃ iron oxide NPs 提高81.4%[95] 7 heat pretreated sludge sugarcane bagasse pH 5.0,30℃ Fe3O4 NPs 提高69.6%[96] 8 anaerobic sludge paper mill waste water pH 7.5 Fe3O4 NPs 提高127.4%[97] 9 Parageobacillus thermoglucosidasius KCTC 33548 glucose, starch pH 6.5,55℃ Fe3O4 NPs 提高315%[98] 10 heat pretreated sludge grass pH 7,37℃ Fe0 NPs / biochar 提高89.8%[99] 11 anaerobic bacteria glucose pH 7,30℃ Fe0 NPs / activated carbon 提高50.2%[100] 12 Enterobacter aerogenes glucose pH 6.8,37℃ Fe0 NPs /chitosan 提高30%[29] 13 Clostridium pasteurianum glucose pH 7,35℃ α-Fe2O3&TiO2 NPs 提高24.9%[101] 14 anaerobic mixed bacteria glucose pH 7,37℃ Fe2O3-Fe3O4 NPs /carbon 提高33.7%[102] 15 Enterobacter aerogenes fruit waste pH 6.5,37℃ Fe3O4 NPs /DSAC 提高204.5%[103] 16 mixed culture bacteria gelatinaceous wastewater pH 6,35℃ Fe3O4/graphene oxide 提高41.9%[104] 17 Enterobacter aerogenes glucose pH 6,37℃ ferric citrate NPs 提高50.45%[105] 18 mesophilic bacteria starch pH 5.0~6.0,37℃ Fe0 NPs, Ni0 NPs 提高37%[2] 19 Clostridium butyricum glucose, starch pH 6.8,37℃ Fe0 NPs&Ni0 NPs 提高28%[106] 20 hydrogen-producing bacteria anaerobic sludge pH 5.0,37℃ Fe2O3 NPs, NiO NPs 分别提高24%和16%[107] 21 thermophilic mixed bacteria glucose pH 5.5,60℃ α-Fe2O3 NPs, NiO NPs 分别提高34.38%和5.47%[4] 22 mixed consortia glucose pH 5.6,35℃ Ni NPs 提高22.71%[108] 23 Clostridium butyricum glucose pH6.9,37℃,55℃ NiFe2O4 NPs 分别提高38.6%(37℃),28.3%(55℃)[30] 24 Bacillus anthracis palm oil pH 7,37℃ NiO NPs, CoO NPs 分别提高151%和167%[21] 25 Clostridium beijerinckii rice mill wastewater pH 7,37℃ NiO NPs, CoO NPs 分别提高109%和90.4%[109] 26 Clostridiumbutyricum glucose pH 7.6,30℃ Fe NPs@SiO2, Pd NPs@SiO2, Ag NPs@SiO2, Cu NPs/SiO2 提高38%[110] 27 mixed consortia glucose pH 5.5,50℃ ZnO NPs 提高29%[111] 28 Clostridiumbutyricum sucrose pH 7.2,35℃ Au NPs 提高61.7%[38] 29 Enterobacter cloacae glucose pH 7,37℃ Pd(Ⅱ) NPs 在单一菌种和混合菌种培养条件下分别提高1.5%和9%[112] 30 mixed culture dominated by Clostridium species glucose pH 8.0~9.4,35℃ Ag NPs 提高67.3%[113]