化工学报 ›› 2011, Vol. 62 ›› Issue (S2): 155-159.DOI: 10.3969/j.issn.0438-1157.2011.z2.028

• 材料化学工程与纳米技术 • 上一篇    下一篇

可聚合的酸性功能化离子液体的合成及表征

童声,范杰平,肖竹芸,田泽由   

  1. 南昌大学环境与化学工程学院
  • 收稿日期:2011-11-04 出版日期:2011-12-20 发布日期:2011-12-20
  • 通讯作者: 范杰平

Synthesis and character of polymerizable Bonsted acidic imidazolium-typed ionic liquids

TONG Sheng,FAN Jieping,XIAO Zhuyun,TIAN Zeyou   

  • Received:2011-11-04 Online:2011-12-20 Published:2011-12-20

摘要: 以1-乙烯基咪唑为原料,分别与溴乙酸、3-溴丙酸、5-溴戊酸、6-溴己酸一步合成反应,得到几种可聚合酸性离子液体。离子液体的酸度采用酸度计和吡啶红外光谱探针法进行了表征。结果表明,由于咪唑环的吸电子效应,咪唑环的引入提高了对应羧酸的酸性,红外光谱表明羧基咪唑离子液体具有Bronsted酸性,且1-乙烯基-3-乙酸基咪唑溴盐的酸性最强,它们可分别与乙二醇二甲基丙烯酸酯进行沉淀聚合,得到白色的聚合物。

关键词: 离子液体;红外光谱法, Bronsted酸

Abstract: Several task-specific ionic liquids were prepared by 1-vinylimidazole reacted with bromoacetic acid,3-bromopropionic acid,5-bromovaleric acid and 6-bromohexanoic acid,respectively. Their structures were characterized by 1H NMR and their Bronsted acidities were studied by IR spectra using pyridine as the spectroscopic probe. The results demonstrated that the 1-vinyl-3-acetoxyimidazolium bromide had the strongest acidity among the studied task-specific ionic liquids,the introduction of imidazolium to carboxylic acid can strengthen the acidity of corresponding carboxylic acid because of the electron-withdrawing effects of imidazolium,each task-specific ionic liquid was able to be polymerized with ethylene glycol dimethacrylate to form a white polymer which was characterized by scanning electron microscope.

Key words: ionic liquid, IR-spectrascopy, Bronsted acidity