CIESC Journal ›› 2012, Vol. 20 ›› Issue (3): 572-576.

• 香港科技大学化学与生物分子工程系戈登?麦凯教授退休纪念专刊 • 上一篇    下一篇

气相有机化合物在改性TiO2/AC复合光催化剂上的光催化降解动力学

杨青山1, 廖永进2, 毛玲玲3   

  1. 1 Guangzhou Unisun Power Technology Co., Ltd., Guangzhou 510600, China 2 Guangdong Power Test and Research Institute, Guangzhou 510600, China 3 Guangdong Inspection & Quarantine Technology Center, Guangzhou 510623, China
  • 收稿日期:2010-08-11 修回日期:2011-11-12 出版日期:2012-06-28 发布日期:2011-11-12

Kinetics of photocatalytic degradation of gaseous organic compounds on modified TiO2/AC composite photocatalyst

YANG Qing-Shan1, LIAO Yong-Jin2, MAO Ling-Ling3   

  1. 1 Guangzhou Unisun Power Technology Co., Ltd., Guangzhou 510600, China 2 Guangdong Power Test and Research Institute, Guangzhou 510600, China 3 Guangdong Inspection & Quarantine Technology Center, Guangzhou 510623, China
  • Received:2010-08-11 Revised:2011-11-12 Online:2012-06-28 Published:2011-11-12

摘要: This study is focused on the kinetic characteristics of photocatalytic degradation of gaseous organic compounds on modified titanium dioxide/activated carbon composite photocatalyst (MTA). The MTA, which co-doping with iron (Fe) and nitrogen (N), was synthesized by a sol-gel method, and its photocatalytic performance was investigated under different reaction conditions. The experimental data obtained were tested by the zero, first and second order kinetic model, and the factors affecting the kinetic model were analyzed. It was clearly demonstrated that the experimental data of toluene and acetone on MTA fit quite well with second order kinetic model equation, but the experimental data of formaldehyde fits well with zero order kinetic model equation.

关键词: titanium dioxide, activated carbon, photocatalyst, kinetic model

Abstract: This study is focused on the kinetic characteristics of photocatalytic degradation of gaseous organic compounds on modified titanium dioxide/activated carbon composite photocatalyst (MTA). The MTA, which co-doping with iron (Fe) and nitrogen (N), was synthesized by a sol-gel method, and its photocatalytic performance was investigated under different reaction conditions. The experimental data obtained were tested by the zero, first and second order kinetic model, and the factors affecting the kinetic model were analyzed. It was clearly demonstrated that the experimental data of toluene and acetone on MTA fit quite well with second order kinetic model equation, but the experimental data of formaldehyde fits well with zero order kinetic model equation.

Key words: titanium dioxide, activated carbon, photocatalyst, kinetic model