CIESC Journal

• Volume 1 • 上一篇    下一篇

REACTION MECHANISM AND FORCED CONCENTRATION OSCILLATION CHARACTERISTICS OF BENZENE OXIDATION PROCESS

张濂; 朱海东   

  1. UNILAB Research Center of Chemical Reaction Engineering, East China Institule of Chemical Technology, Shanghai 200237, China
  • 收稿日期:1992-01-06 修回日期:1992-10-11 出版日期:1993-03-28 发布日期:1993-03-28
  • 通讯作者: 张濂

REACTION MECHANISM AND FORCED CONCENTRATION OSCILLATION CHARACTERISTICS OF BENZENE OXIDATION PROCESS

ZHANG Lian; ZHU Haidong   

  1. UNILAB Research Center of Chemical Reaction Engineering, East China Institule of Chemical Technology, Shanghai 200237, China
  • Received:1992-01-06 Revised:1992-10-11 Online:1993-03-28 Published:1993-03-28
  • Contact: ZHANG Lian

摘要: By combining results of transient response tests with forced concentration oscillation experi-ments,behaviors of benzene oxidation over V_2O_5 catalysts has been determined.Product increse canbe observed during periodic operation.The mechanism of catalytic reaction can be elucidated andthe behavior of concentration oscillation during the reaction is determined.The relation betweencycling frequency and response characteristics has also been studied with two different types of peri-odic operation,i.e.,regular and irregular square waves.

关键词: transient response;forced concentration oscillation;catalytic reaction;benzene

Abstract: By combining results of transient response tests with forced concentration oscillation experi-ments,behaviors of benzene oxidation over V_2O_5 catalysts has been determined.Product increse canbe observed during periodic operation.The mechanism of catalytic reaction can be elucidated andthe behavior of concentration oscillation during the reaction is determined.The relation betweencycling frequency and response characteristics has also been studied with two different types of peri-odic operation,i.e.,regular and irregular square waves.

Key words: transient response, forced concentration oscillation, catalytic reaction, benzene