污水污泥裂解油中多环芳烃的分析

doi:10.3969/j.issn.0438-1157.2013.06.043

化工学报 ›› 2013, Vol. 64 ›› Issue (6): 2227-2231.DOI: 10.3969/j.issn.0438-1157.2013.06.043

污水污泥裂解油中多环芳烃的分析

胡艳军, 管志超, 郑小艳

浙江工业大学能源与动力工程研究所,浙江杭州 310023

收稿日期:2012-11-29 修回日期:2013-01-15 出版日期:2013-06-05 发布日期:2013-06-05
通讯作者: 胡艳军(1979—),女,博士,副教授。
作者简介:胡艳军(1979—),女,博士,副教授。
基金资助:
国家自然科学基金项目(51008279);浙江省自然科学基金项目(Y5100258)。

Analysis on polycyclic aromatic hydrocarbons in pyrolysis oil from municipal wastewater sewage sludge

HU Yanjun, GUAN Zhichao, ZHENG Xiaoyan

Institute of Energy and Power Engineering, Zhejiang University of Technology, Hangzhou 310023, Zhejiang, China

Received:2012-11-29 Revised:2013-01-15 Online:2013-06-05 Published:2013-06-05
Supported by:
supported by the National Natural Science Foundation of China(51008279)and Zhejiang Provincial Natural Science Foundation(Y5100258).

摘要/Abstract

关键词: 污水污泥, 裂解油, 多环芳烃, 回收率

Abstract: Pretreatment of oil samples from pyrolysis of wastewater sewage sludge was carried out using combination route of extraction, enrichment and purification for determining PAHs.Quantitative and qualitative analysis of PAHs were then conducted by GC-MS.16 kinds of PAHs were detected out in sludge pyrolysis oil.The recovery ratio of PAHs is above 80% except for naphthalene on the basis of the constructed pretreatment method and GC-MS analysis condition.Finally, distribution of PAHs was also investigated using experimental tests in three sludge pyrolysis oil samples produced from various ending temperature and heating rate.The total content of the target PAHs in three oil samples is from 2.3 mg·kg^-1 to 47.8 mg·kg^-1.In addition, the ending temperature and heating rate have evident influences on PAHs concentrations in sludge pyrolysis oil.

Key words: wastewater sewage sludge, pyrolysis oil, polycyclic aromatic hydrocarbons, recovery ratio

中图分类号:

胡艳军, 管志超, 郑小艳. 污水污泥裂解油中多环芳烃的分析[J]. 化工学报, 2013, 64(6): 2227-2231.

HU Yanjun, GUAN Zhichao, ZHENG Xiaoyan. Analysis on polycyclic aromatic hydrocarbons in pyrolysis oil from municipal wastewater sewage sludge[J]. CIESC Journal, 2013, 64(6): 2227-2231.

参考文献 15

[1]	Fytili D, Zabaniotou A.Utilization of sewage sludge in EU application of old and new methods—a review[J].Renewable and Sustainable Energy Reviews,2008,12(1):116-140
[2]	Yi Yumin(易玉敏),Ning Ping(宁平),Qu Guangfei(瞿广飞), Zhang Renfeng(张仁锋), Liang Yifu(梁艺福), Duan Wei(段伟).Low-temperature pyrolysis process for oil production from sewage sludge[J].Journal of Kunming University of Science and Technology(昆明理工大学学报), 2008,33(3):92-95
[3]	Kim Y, Parker W.A technical and economic evaluation of the pyrolysis of sewage sludge for the production of bio-oil[J].Bioresource Technology, 2008,99(5):1409-1416
[4]	Ji Aimin(姬爱民),Zhang Shuting(张书廷),Xu Hui(徐晖),Li Haiying(李海英),Zhang Huanxin(张焕鑫).Composition and fuel characters of gasoline-like fraction in the pyrolysis oil of sludge[J].Journal of Fuel Chemistry and Technology(燃料化学学报), 2011,39(3):194-197
[5]	Xiao Benyi(肖本益), Liu Junxin(刘俊新).Effects of various pretreatments on biohydrogen production from sewage sludge[J].Chinese Science Bulletin, 2009,54(12):2038-2044
[6]	Tsai Wen-Tien, Mi Hsiao-Hsuan, Chang Jeng-Hung, Chang Yuan-Ming. Levels of polycyclic aromatic hydrocarbons in the bio-oils from induction-heating pyrolysis of food-processing sewage sludges[J].Journal Analysis Application Pyrolysis, 2009,86:364-368
[7]	Pan Yiting(潘一廷), He Guangxiang(何广湘), Jiao Yuhai(焦玉海), Jin Haibo(靳海波).Study on the oil fractions produced from sewage sludge by low temperature pyrolysis gas chromatography-mass spectrometry[J].Journal of Chinese Mass Spectrometry Society(质谱学报), 2004,25:109-110
[8]	Li Haiying(李海英), Zhang Shuting(张书廷), Zhao Xinhua(赵新华).Influence of pyrogenation temperature of sewage sludge on product distribution[J].Acta Energiae Solaris Sinica(太阳能学报),2006,27(8):835-840
[9]	Jia Xiangru(贾相如),Jin Baosheng(金保升),Li Rui(李睿).Fast pyrolysis of sewage sludge in a fluidized bed for oil from sludge[J].Journal of Combustion Science and Technology(燃烧科学与技术),2009,15(6):528-534
[10]	Xia Huili(夏慧丽),Ni Xiaoming(倪小明),Chen Menglin(陈孟林),He Xingcun(何星存).The situation of research on PAHs in atmosphere[J].Journal of Guangxi Normal University(广西师范大学学报), 2003,21(2):67-70
[11]	Santino Orecchio.Assessment of polycyclic aromatic hydrocarbons(PAHs)in soil of a Natural Reserve(Isola delle Femmine)(Italy)located in front of a plant for the production of cement[J].Journal of Hazardous Materials, 2010,173:358-368
[12]	Fernandez Pilar, Bayona Josep M.Use of off-line gel permeation chromatography-normal-phase liquid chromatography for the determination of polycyclic aromatic compounds in environmental samples and standard reference materials(air particulate matter and marine sediment)[J].Journal of Chromatography, 1992,625(2):141-149
[13]	Xu Hui(徐晖), Lü Lili(吕丽丽), Ding Zongqing(丁宗庆), Yao Jinrong(姚进荣), Pan Wenhui(潘文慧), Zeng Qiang(曾强), Liao Ying(廖颖), Zhu Jinsen(朱金森), Cheng Jing(程靖).Determination of polycyclic aromatic hydrocarbons in soil by microwave-assisted extraction-high performance liquid chromatography[J].Journal of Central China Normal University(华中师范大学学报), 2008,42(4):565-568
[14]	Thomas Wenzl, Rupert Simon, Elke Anklam, Juliane Kleiner.Analytical methods for polycyclic aromatic hydrocarbons(PAHs)in food and the environment needed for new food legislation in the European Union[J].Trends in Analytical Chemistry, 2006,25(7):716-725
[15]	Li Xiaodong(李晓东), Fu Gang(傅钢), You Xiaofang(尤孝方), Yan Jianhua(严建华).A study of the PAHs(polycyclic aromatic hydrocarbons)emissions resulting from the combustion of different ranks of coal[J].Journal of Engineering for Thermal Energy and Power(热能动力工程), 2003,18(2):125-127

污水污泥裂解油中多环芳烃的分析

Analysis on polycyclic aromatic hydrocarbons in pyrolysis oil from municipal wastewater sewage sludge

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 15

相关文章 15

编辑推荐

Metrics

本文评价

[1]	梁斌, 白浩隆, 冯强, 宋华, 蓝天, 刘新华. 民用燃煤颗粒物及多环芳烃排放特性[J]. 化工学报, 2019, 70(8): 2888-2897.
[2]	胡艳军, 余帆, 陈江, 于文静, 卢艳军. 污泥热解过程中多环芳烃排放规律[J]. 化工学报, 2018, 69(8): 3662-3669.
[3]	孟苗苗, 刘应书, 李子宜, 姜理俊, 杨雄, 刘文海. 有序介孔碳对低浓度气相萘的吸附特性分析[J]. 化工学报, 2017, 68(8): 3109-3118.
[4]	杨悦锁, 陈煜, 李盼盼, 武宇辉, 赵传起. 土壤、地下水中重金属和多环芳烃复合污染及修复研究进展[J]. 化工学报, 2017, 68(6): 2219-2232.
[5]	吉红军, 龙涛, 陈墙, 何跃, 林玉锁, 余冉, 祝欣. Tween 80强化-活化过硫酸钠氧化修复多环芳烃污染土壤[J]. 化工学报, 2016, 67(9): 3879-3887.
[6]	胡艳军, 马文超, 吴亚男, 陈江. 不同来源污泥热解油中多环芳烃分布特征[J]. 化工学报, 2016, 67(7): 3016-3022.
[7]	张润楠, 范晓晨, 贺明睿, 苏延磊, 姜忠义. 煤气化废水深度处理与回用研究进展[J]. 化工学报, 2015, 66(9): 3341-3349.
[8]	齐义彬, 李红, 曹美娜, 崔庆锋, 俞理, 董汉平. 一株多环芳烃降解菌吉2及其降解能力[J]. 化工学报, 2015, 66(3): 1072-1079.
[9]	卢绍文, 丁进良, 刘琳琳. 竖炉焙烧过程METSIM动态模拟[J]. 化工学报, 2015, 66(1): 244-250.
[10]	王伟涛, 蒋志国, 张海德, 彭健, 许英豪, 董安华, 杨雪芳, 蒋欣欣. 木瓜蛋白酶在离子液体双水相中的分配行为[J]. 化工学报, 2015, 66(1): 179-185.
[11]	夏天翔, 姜林, 魏萌, 贾晓洋, 钟茂生. 焦化厂土壤中PAHs的热脱附行为及其对土壤性质的影响[J]. 化工学报, 2014, 65(4): 1470-1480.
[12]	李应林, 谭来仔, 张小松. 基于多种状态方程模型的冷凝法油气回收对比[J]. CIESC Journal, 2014, 65(3): 785-791.
[13]	杨红强1，2，丁明山1，2，胡斌1，任嗣利1. 水辅助溶剂法提取油砂中的沥青[J]. 化工进展, 2014, 33(09): 2495-2500.
[14]	于红艳，徐峰，陈红云，杨伟群，杨珍珍. 黑腐酸的改性及其对土壤中多环芳烃的洗脱作用[J]. 化工进展, 2013, 32(03): 697-701.
[15]	贾晓洋，姜林，夏天翔，姚珏君，梁竞，樊艳玲，钟茂生. 焦化厂土壤中的累积、垂向分布特征及来源分析[J]. CIESC Journal, 2011, 62(12): 3525-3531.