非均相催化一步合成碳酸二苯酯的研究（VI）Sn 的添加量对Pd-Sn催化性能的影响

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非均相催化一步合成碳酸二苯酯的研究（VI）Sn 的添加量对Pd-Sn催化性能的影响

张光旭^a,b; 吴元欣^a; 马沛生^b; 田崎峰^a; 吴广文^a,b; 李定或^a

^a Department of Chemical Engineering, Wuhan Institute of Chemical Technology, Wuhan 430074,
China
^b C1National Key Laboratory, Tianjin University, Tianjin 300072, China

收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2004-04-28 发布日期:2004-04-28
通讯作者: 张光旭

Study on Direct Synthesis of Diphenyl Carbonate with Heterogeneous Catalytic Reaction （Ⅵ
） Effect of Sn Loading Method and Content on Activity of Sn-Pd Supported Catalyst

ZHANG Guangxu^a,b; WU Yuanxin^a; MA Peisheng^b; TIAN Qifeng^a; WU Guangwen^a,b; LI Dinghuo^a

^a Department of Chemical Engineering, Wuhan Institute of Chemical Technology, Wuhan 430074,
China
^b C1National Key Laboratory, Tianjin University, Tianjin 300072, China

Received:1900-01-01 Revised:1900-01-01 Online:2004-04-28 Published:2004-04-28
Contact: ZHANG Guangxu

摘要/Abstract

摘要： The compound metal oxide LaxPbyMnzO used as support was prepared by the sol-gel method, and
the catalyst in which Pd was used as active component and Snas co-active component for
direct synthesis of diphenyl carbonate (DPC) with heterogeneous catalytic reaction was
obtained by co-calcination and precipitation respectively.The catalyst was characterized by
XRD, SEM and TEM respectively. The specific surface area of catalysts was measured by
ChemBET3000 instrument, and the activity of the catalysts was tested by the synthesis of
DPC in a pressured reactor. The results showed that when the co-active component Sn was
added by co-calcination method A, its loading content was equal to 14.43% and active
component Pd was loaded by precipitation, the yield and selectivity of DPC could reach
26.78% and 99% respectively.

关键词: 异化反应;钯;锡;催化剂;PC;聚碳酸脂

Abstract: The compound metal oxide LaxPbyMnzO used as support was prepared by the sol-gel method, and
the catalyst in which Pd was used as active component and Snas co-active component for
direct synthesis of diphenyl carbonate (DPC) with heterogeneous catalytic reaction was
obtained by co-calcination and precipitation respectively.The catalyst was characterized by
XRD, SEM and TEM respectively. The specific surface area of catalysts was measured by
ChemBET3000 instrument, and the activity of the catalysts was tested by the synthesis of
DPC in a pressured reactor. The results showed that when the co-active component Sn was
added by co-calcination method A, its loading content was equal to 14.43% and active
component Pd was loaded by precipitation, the yield and selectivity of DPC could reach
26.78% and 99% respectively.

Key words: Sn loading content, diphenyl carbonate, precipitation, co-calcination

张光旭, 吴元欣, 马沛生, 田崎峰, 吴广文, 李定或. 非均相催化一步合成碳酸二苯酯的研究（VI）Sn 的添加量对Pd-Sn催化性能的影响[J]. CIESC Journal.

ZHANG Guangxu, WU Yuanxin, MA Peisheng, TIAN Qifeng, WU Guangwen, LI Dinghuo. Study on Direct Synthesis of Diphenyl Carbonate with Heterogeneous Catalytic Reaction （Ⅵ
） Effect of Sn Loading Method and Content on Activity of Sn-Pd Supported Catalyst[J]. .

非均相催化一步合成碳酸二苯酯的研究（VI）Sn 的添加量对Pd-Sn催化性能的影响

Study on Direct Synthesis of Diphenyl Carbonate with Heterogeneous Catalytic Reaction （Ⅵ
） Effect of Sn Loading Method and Content on Activity of Sn-Pd Supported Catalyst

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非均相催化一步合成碳酸二苯酯的研究（VI）Sn 的添加量对Pd-Sn催化性能的影响

Study on Direct Synthesis of Diphenyl Carbonate with Heterogeneous Catalytic Reaction （Ⅵ ） Effect of Sn Loading Method and Content on Activity of Sn-Pd Supported Catalyst

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Study on Direct Synthesis of Diphenyl Carbonate with Heterogeneous Catalytic Reaction （Ⅵ
） Effect of Sn Loading Method and Content on Activity of Sn-Pd Supported Catalyst