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催化精馏塔中乙酸甲酯水解的研究

王成习   

  1. Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2001-12-28 发布日期:2001-12-28
  • 通讯作者: 王成习

Study on Hydrolysis of Methyl Acetate in a Catalytic Distillation Column

WANG Chengxi   

  1. Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:1900-01-01 Revised:1900-01-01 Online:2001-12-28 Published:2001-12-28
  • Contact: WANG Chengxi

摘要: A nonequilibrium stage model was used to simulate countercurrent multicomponent catalytic
distillation processes for methyl acetate hydrolysis. Computations of stage eiliciencies
or height equivalent to a theoretical plate (HETP) were entirely avoided by this model. The
consistency of simulated results and experimental data in conversions and concentration of
each component along a column indicates that the model predicts the actual process well.
The influences of operating parameters on hydrolytic conversions, such as feed molar
ratios, feed locations, feed and reflux rates, heights of reactive and stripping sections,
were analyzed adequately by simulating calcuiations. A good operating mode was then
obtained, which is helpful to the development of a new process.

关键词: 催化精馏塔;乙酸甲酯;水解;非平衡态级模型;化学反应;乙酸;甲醇

Abstract: A nonequilibrium stage model was used to simulate countercurrent multicomponent catalytic
distillation processes for methyl acetate hydrolysis. Computations of stage eiliciencies
or height equivalent to a theoretical plate (HETP) were entirely avoided by this model. The
consistency of simulated results and experimental data in conversions and concentration of
each component along a column indicates that the model predicts the actual process well.
The influences of operating parameters on hydrolytic conversions, such as feed molar
ratios, feed locations, feed and reflux rates, heights of reactive and stripping sections,
were analyzed adequately by simulating calcuiations. A good operating mode was then
obtained, which is helpful to the development of a new process.

Key words: methyl acetate, hydrolysis, catalytic distillation, nonequilibrium stage model