对二甲苯和醋酸二元液体混合物在不同温度下的超额摩尔体积、粘度和热容

CIESC Journal

• CHEMICAL ENGINEERING DATA • 上一篇下一篇

对二甲苯和醋酸二元液体混合物在不同温度下的超额摩尔体积、粘度和热容

杨长生; 马沛生; 唐多强; 尹秋响; 赵长伟

State Key of C1 Chemistry and Technology, School of Chemical Engineering and Technology,
Tianjin University,Tianjin 300072, China

收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2002-10-28 发布日期:2002-10-28
通讯作者: 杨长生

Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and
Acetic Acid at Different Temperatures

YANG Changsheng; MA Peisheng; TANG Duoqiang; YIN Qiuxiang; ZHAO Changwei

State Key of C1 Chemistry and Technology, School of Chemical Engineering and Technology,
Tianjin University,Tianjin 300072, China

Received:1900-01-01 Revised:1900-01-01 Online:2002-10-28 Published:2002-10-28
Contact: YANG Changsheng

摘要/Abstract

摘要： Experimental densities, viscosities and heat capacities at different temperatures were
presented overthe entire range of mole fraction for the binary mixture of p-xylene and
acetic acid. Density values were used in thedetermination of excess molar volumes, VE. At
the same time, the excess viscosity and excess molar heat capacitieswere calculated. The
values of VE, ηE and cpE were fitted to the Redlich-Kister equation. Good agreements
wereobserved. The excess molar volumes are positive with a large maximum value located in
the central concentrationrange. The excess viscosity has an opposite trend to the excess
molar volume VE. ηE values are negative over theentire range of the mixture. The cure of
dependence of cEp on concentration has a special shape. The molecularinteraction between p
-xylene and acetic acid is discussed.

关键词: viscosity;heat capacity;density;excess molar volume;molecular interaction

Abstract: Experimental densities, viscosities and heat capacities at different temperatures were
presented overthe entire range of mole fraction for the binary mixture of p-xylene and
acetic acid. Density values were used in thedetermination of excess molar volumes, VE. At
the same time, the excess viscosity and excess molar heat capacitieswere calculated. The
values of VE, ηE and cpE were fitted to the Redlich-Kister equation. Good agreements
wereobserved. The excess molar volumes are positive with a large maximum value located in
the central concentrationrange. The excess viscosity has an opposite trend to the excess
molar volume VE. ηE values are negative over theentire range of the mixture. The cure of
dependence of cEp on concentration has a special shape. The molecularinteraction between p
-xylene and acetic acid is discussed.

Key words: viscosity, heat capacity, density, excess molar volume, molecular interaction

杨长生, 马沛生, 唐多强, 尹秋响, 赵长伟. 对二甲苯和醋酸二元液体混合物在不同温度下的超额摩尔体积、粘度和热容[J]. CIESC Journal.

YANG Changsheng, MA Peisheng, TANG Duoqiang, YIN Qiuxiang, ZHAO Changwei. Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and
Acetic Acid at Different Temperatures[J]. .

参考文献

[1] Dean, J.A., Lange’s Handbook of Chemistry, 15th ed.,McGraw-Hill Book Co., NewYork, 220
-290 (1999).
[2] Zhang, X.Y., Handbook of Chemistry, Country defense Industry Book Co., Beijing, 350-381
(1986). (in Chinese)
[3] Martin, J.E., Andon, R.J.L., "Thermodynamic propertiesof ethanoic, propanoic, and
butanic acids", J. Chem. Thermodynam., 14 (8), 679-688(1982).
[4] Oswal, S.L., Patel, A.T., "Viscosity of binary mixture", Int.J. Thermophysics, 13 (4),
629-641 (1992).
[5] Messerly, J.F., Finke, H.L. Good, W.D., "Condensedphase heat capacities and derived
thermodynamic properties for 1,4-dimethylbenzene, 1,2-diphnylene, and 2,3-dimethyl-
naphthalene," J. Chem. Theronodynam., 20 (4),485-501 (1988).
[6] Tardajos, G., Aicart, E., Aicart, E., Costas, M., Pafferson,D., "Liquid structure and
second-order mixing functions forbenzene, toluene and p-xylene with n-alkanes", J.
Chem.Soc. Faraday. Frans., 82 (4), 2977-2987 (1986).
[7] Ott, J.B., Goate, J.R., Grigg, R.B., "Excess volumes, entralpies and Gibbs free
energies for mixture of benzenes+p-xylene", J. Chem. Thermodynam., 11 (2), 1167-1173(1979).
[8] Tu, C.H., Lee, S.L., Peng, I.H., "Excess volumes and viscosities of binary mixture of
aliphatic alcohols(C1-C4)with nitromethane", J. Chem. Eng. Data., 46 (1), 151-160 (2001).
[9] Oswal, S.L., Pater, I.N., "Thermodynamic interaction inbinary mixtures of
ethenylbenzene with methanol, ethanol,butan-l-ol, pentan-1-ol, and hexan-l-ol in the
temperaturerange 298.15-308.15K ", Int. J. Thermophysies, 21 (3),681-693 (2000).
[10] Tejraj, M.A., "Thermodynamic interactions in binary mixture of ethylbenzene with
methanol, ethanol, butan-l-ol inthe temperature range 298.15-308.15 K", J. Chem. Eng.Data,
44 (6), 1291-1297 (1999).
[11] Aalendu, P., Gurcharam, D., "Excess molar volumes andviscosities for binary liquid
mixtures of 2-propoxyethanoland 2-isopropoxythanol with methanol, 1-propanol, 2-propanol,
and 1-pentanol at 298.15K", J. Chem. Eng.Data, 45 (4), 693-698 (2000).
[12] Weng, W.L., "Densites and viscosities for binary mixturesof butylamine with aliphatic
alcohols", J. Chem. Eng.Data, 45 (4), 606-609 (2000).
[13] Pondharinath, S., Nikam, B., "Densities and viscosities ofbinary mixture of toluene
with methanol, ethanol, propan1-ol, pentan-l-ol, and 2-merylpropan-2-ol at (303.15,308.15,
313.15K) ", J. Chem. Eng. Data, 45 (4), 559-563 (2000).
[14] Treszczanowica, A.J., Kigohora, O., Benson, G.C., "Excess volumes for n-alkane binary
mixture of decan-1ol+n-pentan, +n-hexane, +n-octane, +n-decane, and nhexadecane", J. Chem.
Thermodyn., 13 (2), 253-260(1981).

对二甲苯和醋酸二元液体混合物在不同温度下的超额摩尔体积、粘度和热容

Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and
Acetic Acid at Different Temperatures

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价

对二甲苯和醋酸二元液体混合物在不同温度下的超额摩尔体积、粘度和热容

Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and Acetic Acid at Different Temperatures

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价

Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and
Acetic Acid at Different Temperatures