CIESC Journal

• 化工学报 • 上一篇    下一篇

滴外传质系数的研究

苏元复,卢鸿业,毛之侯,陈同芸   

  1. 华东化工学院 ,华东化工学院 ,华东化工学院 ,华东化工学院
  • 出版日期:1965-12-25 发布日期:1965-12-25

ON THE CONTINUOUS PHASE MASS-TRANSFER COEFFICIENTS OF SINGLE DROPS

Hwa-tung Institute of Chemical Technology Su YUAN-FU, Lu HUNG-I, MAO TSE-HOU AND CHENG TUNG-YUNG   

  • Online:1965-12-25 Published:1965-12-25

摘要: 作者采用四个体系,测定有机溶剂液滴在水相中自由下降时溶质的传递速率。所选择的溶质,其分配系数均极有利于有机相,故滴内阻力可以略而不计。 实验中竭力防止系统的沾染,获得了重现性好的实验数据。作者比较了计算滴外系数的各种关系式的适用性,发现各式仅在一定的范围内适合。并提出了纯物系和实际萃取过程中沾染物系的滴外传质系数的一般关联方法。 在所选择的体系的浓度范围内,以光纹技术进行观察,当液滴悬垂于静止的水溶液中,未发现可察觉的介面骚动现象,故作者提出的一般关联方法仅能适用于无介面骚动现象的传质过程。

Abstract: Four ternary systems have been used for the determination of mass transfer rates between single organic drops and aqueous solutions. The solutes chosen are highly in favor of organic dispersed phase so that the resistance can be considered solely in the continuous aqueous phase. In the experiments for pure systems, special attention has been paid to the purification of all substances employed and to the avoidance of possible contaminations of apparatus and both liquids, and reproducible mass transfer results can thus be obtained over the range of drop Reynolds number between 4 and 1000. These data have been used to test various correlations proposed by different authors, and it has been found that each correlation can fit only a limited range of drop Reynolds number, i.e. at Re≤50, the measured continuous phase coefficients essentially follow those of solid spheres during dissolution, at Re≥1000, nearly agree with those predicted from the equation proposed by Handles and Baron[26], and at 100