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由合成气生产二甲醚过程反应协同作用的研究

王志良; 刁杰; 王金福; 金涌   

  1. Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2001-12-28 发布日期:2001-12-28
  • 通讯作者: 王志良

Study on Synergy Effect in Dimethyl Ether Synthesis from Syngas

WANG Zhiliang; DIAO Jie; WANG Jinfu; JIN Yong   

  1. Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
  • Received:1900-01-01 Revised:1900-01-01 Online:2001-12-28 Published:2001-12-28
  • Contact: WANG Zhiliang

摘要: Influence of reaction temperature, pressure and space velocity on the direct synthesis of
dimethyl ether (DME) from syngas is studied in an isothermal fixed-bed reactor. The
catalyst is a physical mixture of C30 copper-based methanol (MeOH) synthesis catalyst and
ZSM-5 dehydration catalyst. The experimental results show that the chemical synergy between
methanol synthesis reaction and methanol dehydration reaction is evident. The conversion of
carbon monoxide is over 90%.

关键词: 合成气;化工生产;二甲醚;反应过程;协同作用;甲醇脱水;化学合成

Abstract: Influence of reaction temperature, pressure and space velocity on the direct synthesis of
dimethyl ether (DME) from syngas is studied in an isothermal fixed-bed reactor. The
catalyst is a physical mixture of C30 copper-based methanol (MeOH) synthesis catalyst and
ZSM-5 dehydration catalyst. The experimental results show that the chemical synergy between
methanol synthesis reaction and methanol dehydration reaction is evident. The conversion of
carbon monoxide is over 90%.

Key words: dimethyl ether, chemical synergy, methanol dehydration, syngas