CIESC Journal

• 材料化学工程与纳米技术 • 上一篇    下一篇

模板法制备二氧化硅纳米管及其表征

郑斌;李元庆;朱路平;杨洋;付绍云   

  1. 中国科学院理化技术研究所
  • 出版日期:2007-10-05 发布日期:2007-10-05

Silica nanotubes synthesized from TEOS with ammonium D,L-tartrate as template and their characterization

ZHENG Bin;LI Yuanqing;ZHU Luping;YANG Yang;FU Shaoyun   

  • Online:2007-10-05 Published:2007-10-05

摘要:

以正硅酸乙酯(TEOS)为原料,D〖DK〗,L酒石酸铵为模板制备了高产率、尺寸均匀、大长径比的二氧化硅纳米管。借助透射电子显微(TEM)、扫描电子显微(SEM)、电子能谱(EDX)和X射线衍射(XRD)等分析方法对样品进行表征,探讨了二氧化硅纳米管的形成机理,并考察了实验条件对二氧化硅纳米管的产率和形貌等的影响。研究结果表明,静置时间、TEOS的滴加速率以及氨水用量对纳米管的形成有明显影响,而温度对纳米管形成的影响不明显。

Abstract:

Silica nanotubes with high yield,uniform size and large aspect ratio were synthesized from hydrodyzing tetraethyl orthosilicate(TEOS)using ammonium D,L-tartrate as templateThe prepared products were characterized with transmission electron microscopy(TEM),scanning electron microscopy(SEM),energy dispersive Xray analysis(EDX)and powder X-ray diffraction(XRD)The formation mechanism of the silica nanotubes and the influence of synthesis conditions on the formation of the silica nanotubes were investigatedThe results revealed that the morphology and yield of the silica nanotubes were sensitive to TEOS addition speed,aging time after TEOS addition and ammonia concentration,but not sensitive to reaction temperature.