化工学报 ›› 2010, Vol. 61 ›› Issue (5): 1219-1225.

• 能源和环境工程 • 上一篇    下一篇

气流床煤气化炉壁面反应模型

刘升,郝英立,杜敏,陶明春   

  1. 东南大学能源与环境学院;东南大学空间科学与技术研究院
  • 出版日期:2010-05-05 发布日期:2010-05-05

A model of wall reaction in entrained-flow coal gasifier

LIU Sheng, HAO Yingli, DU Min, TAO Mingchun   

  • Online:2010-05-05 Published:2010-05-05

摘要:

建立了气流床煤气化炉煤灰渣颗粒沉积和壁面反应模型,相应完善了渣层流动、传热传质和相变模型,发展了数值模拟方法,并以国内某型两段式干煤粉加压气流床煤气化中试炉为对象进行了模拟。利用建立的模型可以得到壁面反应速率、渣层含碳量、固态渣层厚度、液态渣层厚度、渣层平均温度和液态渣层平均速度等。结果表明:氧煤比升高,渣层平均温度升高,固态渣层厚度、液态渣层厚度和气化炉出口灰渣含碳量降低。计算得到的灰渣含碳量在14%左右,整体碳转化率为95.2%左右,与实际值相近。通过模拟发现壁面反应对于所分析气化炉的碳转化率、排渣含碳量、壁面渣层流动和温度状态具有重要影响,进而影响气化炉的安全稳定运行。

关键词:

气流床煤气化炉, 颗粒沉积, 壁面反应, 渣层

Abstract:

A model for the deposition and wall reaction of molten coal ash slag particle in entrained-flow coal gasifier was proposed.The models of flow, heat and mass transfer, and phase change of slag layer in entrained flow coal gasifier were improved.The method of numerical simulation was developed.Simulations were carried out on a Chinese pilot-scale two-stage dry feed entrained-flow gasifier.The carbon content of slag layer, wall reaction rate, thicknesses of solid slag layer and liquid slag layer, average temperature of slag layer, and average velocity of liquid slag layer were obtained with the proposed model.With increasing oxygen to coal ratio, the thicknesses of solid slag layer and liquid slag layer and carbon content of slag layer at the outlet of gasifier decreased, 〖HJ*4/9〗while the average temperature of slag layer increased.The carbon content of slag was about 14%, and carbon conversion of the gasifier was 95.2%, which agreed with the experiment data.It was revealed that wall reaction had significant effects on carbon conversion, carbon content of slag, flow and temperature of slag layer in the gasifier.It might affect the reliability of practical operation of the gasifier.

Key words:

气流床煤气化炉, 颗粒沉积, 壁面反应, 渣层