CIESC Journal

• 催化、动力学与反应器 • 上一篇    下一篇

旋转填充床内微观混合化学反应计算数学模型

邱崑玉;吕和祥;陈建峰   

  1. 大连理工大学工业装备结构分析国家重点实验室,辽宁 大连 116023;北京化工大学教育部超重力工程研究中心,北京 100029

  • 出版日期:2005-07-25 发布日期:2005-07-25

Mathematical model for calculating micro-mixingchemical reaction in rotating packed bed

QIU Kunyu;LV Hexiang;CHEN Jianfeng

  

  • Online:2005-07-25 Published:2005-07-25

摘要: 在层状扩散模型的基础上, 以1-萘酚与对氨基苯磺酸重氮盐在旋转填充床内发生的竞争串联偶氮化合反应为例,探讨了填充床内的微观混合情况.引进了两个调整反应物与生成物关系的参数,对整个反应过程建立了一个计算数学模型;并进行了计算,计算预测的结果与实验数据在规律上和数值上都较好符合.

Abstract: Based on the laminar diffusion model, the micro-mixing in a rotating packed bed (RPB) was discussed by taking the competitive and consecutive azobenzene reaction between 1-naphthol and diazotised sulphanilic acid as reaction system. A mathematical model was presented to describe the whole process of the reaction by introducing two parameters that could impose adjustment between the reactants and the resultants. The reaction was calculated and the results were consistent with the experimental data.