CIESC Journal

• 催化、动力学与反应器 • 上一篇    下一篇

竹材热解过程的动力学

曾凯斌;蒋斌波;陈纪忠   

  1. 浙江大学化学工程与生物工程学系,浙江 杭州 310027

  • 出版日期:2006-02-25 发布日期:2006-02-25

Kinetics of bamboo pyrolysis

ZENG Kaibin;JIANG Binbo;CHEN Jizhong   

  • Online:2006-02-25 Published:2006-02-25

摘要: 在不同升温速率(5、10、20、30 K•min-1)下,对竹材进行TG、DTG分析.试样从313~650 K的升温过程经历了水分析出﹑第一步热解和第二步热解过程.用Levenberg-Marquardt方法对非等温动力学过程进行数据拟合,结果表明,半纤维素在较低温度下热解,仅生成挥发性组分,表现为第一步热解,可以用简单一级反应描述;纤维素和木质素在较高温度下热解,表现为第二步热解,是竞争的平行一级反应,产物分别是挥发性组分和竹炭.第一热解过程与热解升温速率有关,而第二热解过程与升温速率无关.

Abstract: Bamboo materials were pyrolyzed in TGA equipment (TGA/SDTA851e) at heating rate of 5,10,20,30 K•min-1 in the temperature range of 313~650 K and N2 atmosphere.The pyrolysis process of bamboo consisted of three steps: pre-pyrolysis of water evaporation,first step pyrolysis and second step pyrolysis. The kinetics of bamboo pyrolysis was analyzed based on the Levenberg-Marquardt method. The first step of bamboo pyrolysis could be considered as the pyrolysis of semi-cellulose to volatile matter only and well described by a first-order reaction model.The second step of bamboo pyrolysis could be considered as the pyrolysis of cellulose and lignin to volatile matter and char,and well described by a parallel first-order reaction model.The first step of bamboo pyrolysis was dependent on heat-up rate,while the second step of bamboo pyrolysis was independent of heat-up rate.