化工学报 ›› 2004, Vol. 55 ›› Issue (4): 649-652.
• 催化、动力学与反应器 • 上一篇 下一篇
刘欣一; 王树东; 周谨
出版日期:
发布日期:
LIU Xinyi;WANG Shudong;ZHOU Jin
Online:
Published:
关键词: 变换反应, 铂/铈锆氧化物, 本征动力学
Abstract: The intrinsic kinetics of water gas shift reaction over Pt/CeO2-ZrO2 was investigated.Experiments were carried out by means of orthogonal design.Parameters of power-type rate model of water gas shift reaction were determined by the non-linear least-square parameter estimation method.The kinetics of water gas shift reaction over Pt/CeO2-ZrO2 was different from that of common commercial catalysts.The accuracy of experimental data and kinetics model was proved by F-examination.
Key words: 变换反应, 铂/铈锆氧化物, 本征动力学
刘欣一, 王树东, 周谨. Pt/CeO2-ZrO2催化剂上的CO变换反应本征动力学 [J]. 化工学报, 2004, 55(4): 649-652.
LIU Xinyi, WANG Shudong, ZHOU Jin. INTRINSIC KINETICS OF WATER GAS SHIFT REACTION OVER Pt/CeO2-ZrO2[J]. CIESC Journal, 2004, 55(4): 649-652.
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