CIESC Journal

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超(亚)临界CO2中涂料基体的相行为研究

曹维良; 徐金龙; 张敬畅   

  1. Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China


  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2003-04-28 发布日期:2003-04-28
  • 通讯作者: 曹维良

Study on the Phase Behavior of Coating Matrix in Supercritical or Sub-critical Carbon
Dioxide

CAO Weiliang; XU Jinlong; ZHANG Jingchang   

  1. Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China


  • Received:1900-01-01 Revised:1900-01-01 Online:2003-04-28 Published:2003-04-28
  • Contact: CAO Weiliang

摘要: The high-pressure phase behavior of coating-solvent-supercritical or sub-critical carbon
dioxide system was investigated experimentally. The coating matrix used was 108-acrylic
resin at concentration ranging from 10% to 50% (by mass) in mixtures with n-butyl acetate.
The experiments were conducted in a high-pressure view cell for temperatures from 35℃ to
65℃ and for pressures from 3.0 MPa to 8.0 MPa. The effect of temperature, pressure and
content of every component on the phase behavior of the systems was observed. Finally, the
ternary phase diagram for resin-solvent-CO2 was plotted.

关键词: phase behavior;supercritical CO2;coating matrix

Abstract: The high-pressure phase behavior of coating-solvent-supercritical or sub-critical carbon
dioxide system was investigated experimentally. The coating matrix used was 108-acrylic
resin at concentration ranging from 10% to 50% (by mass) in mixtures with n-butyl acetate.
The experiments were conducted in a high-pressure view cell for temperatures from 35℃ to
65℃ and for pressures from 3.0 MPa to 8.0 MPa. The effect of temperature, pressure and
content of every component on the phase behavior of the systems was observed. Finally, the
ternary phase diagram for resin-solvent-CO2 was plotted.

Key words: phase behavior, supercritical CO2, coating matrix