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乙烯-苯-乙苯三元系临界温度和临界压力研究

孙明华; 叶汝强; 刘涛; 刘洪来   

  1. Department of Chemistry, East China University of Science and Technology, Shanghai 200237,
    China
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2002-08-28 发布日期:2002-08-28
  • 通讯作者: 孙明华

Measurements of the Critical Temperature and Pressure of Ethylene+Benzene+Et hylbenzene
Mixture

SUN Minghua; YE Ruqiang; LIU Tao; LIU Honglai   

  1. Department of Chemistry, East China University of Science and Technology, Shanghai 200237,
    China
  • Received:1900-01-01 Revised:1900-01-01 Online:2002-08-28 Published:2002-08-28
  • Contact: SUN Minghua

摘要: Critical temperature (Tc) and critical pressure (pc) of the ternary mixture of ethylene +
benzene + ethylbenzene (the mole ratio of ethylbenzene to benzene was fixed at 0.95:0.05)
were measured by using a highpressure view cell with direct visual observation. The
interaction coefficients obtained from the critical properties of the relevant binary
systems were used to predict the critical properties (Tc, pc) of the ternary mixture. The
agreement between the prediction and experiments is satisfactory.

关键词: critical property;ternary mixture;benzene;ethylbenzene;ethylene

Abstract: Critical temperature (Tc) and critical pressure (pc) of the ternary mixture of ethylene +
benzene + ethylbenzene (the mole ratio of ethylbenzene to benzene was fixed at 0.95:0.05)
were measured by using a highpressure view cell with direct visual observation. The
interaction coefficients obtained from the critical properties of the relevant binary
systems were used to predict the critical properties (Tc, pc) of the ternary mixture. The
agreement between the prediction and experiments is satisfactory.

Key words: critical property, ternary mixture, benzene, ethylbenzene, ethylene