CIESC Journal

• REACTION KINETICS, CATALYSIS AND…… • 上一篇    下一篇

低品位铌钽矿高浓碱性介质浸出过程动力学研究

周宏明; 郑诗礼; 张懿   

  1. Institute of Process Engineering, Chinese Academy of sciences, Beijing 100080, China
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2004-04-28 发布日期:2004-04-28
  • 通讯作者: 周宏明

Kinetic Investigations on the Leaching of Niobium from a Low-Grade Niobium-Tantalum Ore by
Concentrated KOH Solution

ZHOU Hongming; ZHENG Shili; ZHANG Yi   

  1. Institute of Process Engineering, Chinese Academy of sciences, Beijing 100080, China
  • Received:1900-01-01 Revised:1900-01-01 Online:2004-04-28 Published:2004-04-28
  • Contact: ZHOU Hongming

摘要: The leaching kinetics of niobium from a low-gr~te niobium-tantalum ore by concentrated KOH
solution under atmospheric pressure has been studied. Significant effects of reaction
temperature, KOH concentration,stirring speed, particle size and mass ratio of alkali-to-
ore on the dissolution rate of niobiumwere examined. The experimental data of the leaching
rates and the observed effects of the relevant operating variables were well interpreted
with a shrinking core model under diffusion control. By using the Arrhenius expression, the
apparent activation energy for the dissolution of niobium was evaluated. Finally, on the
base of the shrinking core model, the rate equation was established.

关键词: 铌;动力学;过滤技术;钽;KOH;扩散控制;温度

Abstract: The leaching kinetics of niobium from a low-gr~te niobium-tantalum ore by concentrated KOH
solution under atmospheric pressure has been studied. Significant effects of reaction
temperature, KOH concentration,stirring speed, particle size and mass ratio of alkali-to-
ore on the dissolution rate of niobiumwere examined. The experimental data of the leaching
rates and the observed effects of the relevant operating variables were well interpreted
with a shrinking core model under diffusion control. By using the Arrhenius expression, the
apparent activation energy for the dissolution of niobium was evaluated. Finally, on the
base of the shrinking core model, the rate equation was established.

Key words: clean process, leaching, kinetics, KOH, niobium-tantalum ore, diffusion control