化工学报 ›› 2009, Vol. 60 ›› Issue (8): 2095-2100.
• 能源和环境工程 • 上一篇 下一篇
綦峥;祁佩时;杨巍
出版日期:
发布日期:
QI Zheng;QI Peishi;YANG Wei
Online:
Published:
关键词: 水滑石层片, 接枝聚合, 无机-有机杂化聚两性电解质, 泡沫分散体系
水滑石层片,
Abstract:
Mg3Al layered double hydroxides (Mg3Al-LDHEPCL) was grafted through free radical polymerization using S2O2-8/S2O2-5 redox initiator.Monomers used for the graft copolymerization were composed of anionic monomers acrylic acid (AA) and sodium acrylate (SA) as well as cationic monomers trimethylallyl ammonium chloride (TMAAC) and dimethyldiallyl ammonium chloride (DMDAAC).The produced hybrid graft copolymer, Mg3Al-LDHEPCL-g-PAA-PSA-co-PTMAAC-co-PDMDAAC, can be used as polyampholyte sewage treatment agent.The graft copolymerization process was monitored by differential scanning calorimetry (DSC) to obtain the kinetic characteristics in the foamed dispersion polymerization system.The graft copolymerization composition was optimized aiming to achieve lower water content in the sludge and lower COD value in the filtrate.The optimized composition was found to be m(Mg3Al-LDHEPCL )∶m(AA+SA+TMAAC+DMDAAC)=0.12∶1;m(TMAAC+DMDAAC)∶m(AA+SA+TMAAC+DMDAAC)=0.288∶0.712, and the neutralization ratio of AA was 18%—24%.Hydrolysis analog studies in 1.0 mol8226;L-1 NaOH solution revealed that the layered cluster of Mg3Al-LDHEPCL hydrolyzed into multiple lamellar segments forming a secondary quaternary ammonium polyampholyte that functioned as coagulation agent.These inherent structural characteristics are important factors for improving the dehydration effect significantly.The crystal structures were characterized by XRD and IR.
Key words: 水滑石层片, 接枝聚合, 无机-有机杂化聚两性电解质, 泡沫分散体系
綦峥, 祁佩时, 杨巍. 新型聚两性电解质污水处理剂的制备 [J]. 化工学报, 2009, 60(8): 2095-2100.
QI Zheng, QI Peishi, YANG Wei. Preparation of novel polyampholyte water treatment agent[J]. CIESC Journal, 2009, 60(8): 2095-2100.
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表面接枝二分散聚合物的自洽场理论