新生态铁的在线生成及在油田废水处理中的应用

doi:10.11949/j.issn.0438-1157.20151262

化工学报 ›› 2016, Vol. 67 ›› Issue (4): 1527-1533.DOI: 10.11949/j.issn.0438-1157.20151262

新生态铁的在线生成及在油田废水处理中的应用

梁倩¹, 段云敏¹, 吴彬彬¹, 张乃东^1,2

1. 大连海事大学环境科学与工程学院, 辽宁大连 116026;
2. 哈尔滨工业大学城市水资源与水环境国家重点实验室, 黑龙江哈尔滨 150090

收稿日期:2015-08-06 修回日期:2015-12-03 出版日期:2016-04-05 发布日期:2016-04-05
通讯作者: 张乃东
基金资助:
哈尔滨工业大学城市水资源与水环境国家重点实验室开放基金项目(QAK201503)。

Newly-formed poly ferric generated online and its application in treating oilfield wastewater

LIANG Qian¹, DUAN Yunmin¹, WU Binbin¹, ZHANG Naidong^1,2

1. College of Environmental Science and Engineering, Dalian Maritime University, Dalian 116026, Liaoning, China;
2. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, Heilongjiang, China

Received:2015-08-06 Revised:2015-12-03 Online:2016-04-05 Published:2016-04-05
Supported by:
supported by the Open Project of State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology (QAK201503).

摘要/Abstract

摘要：

利用Fenton法处理辽河油田采油废水时,通过紫外可见光谱法、红外光谱法(FTIR)及X射线衍射法证明了体系中有聚铁生成,并用逐时络合比色法确定了新生态铁中Fe(Ⅲ)的形态分布,同时对Fenton的氧化和絮凝作用做了分步研究,结果表明,Fenton法具有氧化和絮凝双重作用,二者具有协同效应,其功效大于单纯的聚铁絮凝,也远大于自身的单纯氧化。

关键词: 新生态铁, 聚铁, Fenton试剂, 油田废水

Abstract:

The waste water in oil production in Liaohe Oilfield is treated by Fenton method. It is proved by using UV-Vis spectroscopy, infrared spectroscopy (FTIR) and X-ray diffraction method (XRD) that the poly ferric compounds are generated in the system. The Ferron-complexation timed spectrophotomctric method is used to confirm the species distribution of the newly-formed ferric. At the same time, the process research of Fenton's oxidation and flocculation are studied. The results show that Fenton method has a dual function of oxidation and flocculation, and both of them have synergistic effect. The dual function makes the efficiency higher than that of the separate poly ferric flocculation, and also far greater than separate oxidation of itself.

Key words: newly-formed ferric, poly ferric, Fenton reagent, oilfield wastewater

中图分类号:

X703.1

梁倩, 段云敏, 吴彬彬, 张乃东. 新生态铁的在线生成及在油田废水处理中的应用[J]. 化工学报, 2016, 67(4): 1527-1533.

LIANG Qian, DUAN Yunmin, WU Binbin, ZHANG Naidong. Newly-formed poly ferric generated online and its application in treating oilfield wastewater[J]. CIESC Journal, 2016, 67(4): 1527-1533.

参考文献 19

[1]	BARBARA B, IDA D M, FRANCESCO V. Fenton treatment of complex industrial wastewater: optimization of process conditions by surface response method[J]. Journal of Hazardous Materials, 2011, 186 (2/3): 1733-1738.
[2]	ARTURO A B, DOONYSIOS D D, MAKRAM T S. Effect of oxidant-to-substrate ratios on the degradation of MTBE with Fenton reagent[J].Water Research, 2008, 42 (12): 3225-3239.
[3]	FENG F, XU Z L, LI X H. Advanced treatment of dyeing wastewater towards reuse by the combined Fenton oxidation and membrane bioreactor process[J]. Journal of Environmental Sciences, 2010, 22 (11):1657-1665.
[4]	BOSSMANN S H, OLIVEROS E, GOB S, et al. New evidence against hydroxyl radicals as reactive intermediates in the thermal and photochemically enhanced Fenton reactions[J]. Journal of Physical Chemistry A, 1998, 102 (28): 5542-5550.
[5]	SHENG H L, CHO C L. Fenton process for treatment of desizing wastewater[J]. Water Research, 1997, 31 (8): 2050-2056.
[6]	杨雪, 张景成, 关小红. 新生态铁的混凝作用探索[J]. 环境科学, 2012, 33 (4):1221-1226. YANG X, ZHANG J C, GUAN X H. Exploration of newly-formed ferric as the coagulant[J]. Environmental Science, 2012, 33 (4): 1221-1226.
[7]	周巧利, 乔俊莲, 杨雪, 等. 基于新生态铁的复合混凝剂的净化效能研究[J]. 环境科学与技术, 2013, 36 (12): 139-143. ZHOU Q L,QIAO J L,YANG X, et al. Coagulation performance of freshly-formed ferric composite coagulant[J]. Environmental Science & Technology, 2013, 36 (12): 139-143.
[8]	GUAN X H, MA J, DONG H R. Removal of arsenic from water: effect of calcium ions on As(Ⅲ) removal in the KMnO4-Fe(Ⅱ) process[J]. Water Research, 2009, 43 (20): 5119-5128.
[9]	DE L J, GALLARD H. Catalytic decomposition of hydrogen peroxide by Fe(Ⅲ) in homogeneous aqueous solution: mechanism and kinetic modeling[J]. Environmental Science &Technology, 1999, 33 (16): 2726-2732.
[10]	田宝珍, 汤鸿霄. Ferron逐时络合比色法测定铁(Ⅲ)溶液聚合物的形态[J]. 环境化学, 1989, 8 (4): 27-34. TIAN B Z, TANG H X. Determination of polymeric Fe(Ⅲ) species by ferron-complexation timed spectrophotometric method[J]. Environmental Chemistry, 1989, 8 (4): 27-34.
[11]	常青, 汤鸿霄. 聚合铁的形态特征和凝聚-絮凝机理[J]. 环境科学学报, 1985, 5 (4) :185-194. CHANG Q, TANG H X. Characterization and coagulation-flocculation mechanism of polymeric iron[J]. Acta Scientiae Circumstiae, 1985, 5 (2): 185-194.
[12]	郑怀礼, 彭德军, 黄小红, 等. 聚合硫酸铁絮凝剂的絮凝形态光谱研究[J]. 光谱学与光谱分析, 2007, 27 (12): 2480-2484. ZHENG H L,PENG D J, HUANG X H, et al. Study on the spectrum of the flocculent conformation of polymer ferric[J]. Spectroscopy and Spectral Analysis, 2007, 27 (12): 2480-2484.
[13]	田宝珍, 汤鸿霄. 聚合铁的红外光谱和电导特征[J]. 环境化学, 1990, 9 (6): 73-74. TIAN B Z, TANG H X. Infrared spectra and electrical conductivity of polymeric Fe(Ⅲ) species[J]. Environmental Chemistry, 1990, 9 (6): 73-74.
[14]	晏井春, 朱富坤, 闫永胜, 等. 纳米聚合硫酸铁的制备、表征及应用研究[J]. 无机盐工业, 2007, 39 (11): 27-29. YAN J C, ZHU F K, YAN Y S, et al. Study on preparation, characterization and application of nano-sized polyferric sulfate coagulant[J]. Inorganic Chemicals Industry, 2007, 39 (11): 27-29.
[15]	TANG H X, STUMM W. The coagulation behaviors of Fe(Ⅲ) polymeric species[J]. Water Research, 1987, 21 (1): 115-121.
[16]	杨敏, 高迎新, 王东升, 等. Fe(Ⅲ,Ⅱ)/H2O2体系中Fe(Ⅲ) 水解特征的对比[J]. 环境科学学报, 2003, 23 (2): 174-177. YANG M, GAO Y X, WANG D S, et al. Fe(Ⅲ) hydrolyzing characteristics in Fenton and Fenton-like processes using Ferron assay[J]. Acta Scientiae Circumstiae, 2003, 23 (2): 174-177.
[17]	WALLING C, WEIL T. The ferric ion catalyzed decomposition of hydrogen peroxide in perchloric acid solution[J]. International Journal of Chemical Kinetics, 1974, 6 (4): 507-516.
[18]	WALLING C, KATO S. The oxidation of alcohols by Fenton's reagent: the effect of copper ion[J].Journal of the American Chemical Society, 1971, 93 (17): 4275-4281.
[19]	JIANG C C, PANG S Y, OUYANG F, et al. A new insight into Fenton and Fenton-like processes for water treatment[J]. Journal of Hazardous Materials, 2010, 174 (1/2/3): 813-817.

新生态铁的在线生成及在油田废水处理中的应用

Newly-formed poly ferric generated online and its application in treating oilfield wastewater

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