微悬浮法制备有机颜料微胶囊中的粒径调控

doi:10.3969/j.issn.0438-1157.2013.03.047

化工学报 ›› 2013, Vol. 64 ›› Issue (3): 1118-1123.DOI: 10.3969/j.issn.0438-1157.2013.03.047

• 材料化学工程与纳米技术 • 上一篇下一篇

微悬浮法制备有机颜料微胶囊中的粒径调控

戚栋明, 陈智杰, 赵晓丽, 徐杰, 申兴丛, 杨雷

浙江理工大学生态染整技术教育部工程研究中心,先进纺织材料与制备技术教育部重点实验室,浙江杭州 310018

收稿日期:2012-05-14 修回日期:2012-06-10 出版日期:2013-03-05 发布日期:2013-03-05
通讯作者: 戚栋明(1978—),男,副教授。
作者简介:戚栋明(1978—),男,副教授。
基金资助:
国家自然科学基金项目(50803058,51273182);浙江省自然科学基金项目(Y4100221);浙江省重点创新团队资助项目(2010R50038)。

Particle size control of organic pigment microcapsules prepared via micro-suspension polymerization

QI Dongming, CHEN Zhijie, ZHAO Xiaoli, XU Jie, SHEN Xingcong, YANG Lei

Engineering Research Center of Eco-Dyeing and Finishing of Textiles, Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, Zhejiang, China

Received:2012-05-14 Revised:2012-06-10 Online:2013-03-05 Published:2013-03-05
Supported by:
supported by the National Natural Science Foundation of China(50803058,51273182),the Natural Science Foundation of Zhejiang Province(Y4100221)and the Key Innovation Team of Zhejiang Province(2010R50038).

摘要/Abstract

摘要： 为调控有机颜料微胶囊的粒径及其分布,在分析微悬浮聚合过程粒径变化的基础上,系统研究了微悬浮聚合工艺(均质化剪切速率、搅拌速率)和配方(有机颜料、分散剂含量)对颜料微胶囊粒径的影响。发现当搅拌速率为250 r·min^-1时,单体液滴的融合和乳胶粒的粘并现象均较少,聚合体系可较稳定地保持均质化单体液滴的尺寸。分散剂磷酸三钙TCP用量对体系稳定性影响明显,但其粒径调控能力有限。均质化强度对微胶囊粒径影响明显,具有较好的调控能力,而颜料含量对微胶囊粒径的影响较少。因而通过聚合工艺和配方的综合调节,可制得一系列颜料含量高、粒径分布窄、粒径可调范围较大的"石榴状"有机颜料微胶囊。

关键词: 颜料微胶囊, 微悬浮聚合, 粒径调控

Abstract: Hydrophobic copper phthalocyanine blue organic pigment (PB) can be effectively encapsulated by co-poly(styrene-acrylate)via in-situ micro-suspension polymerization.In order to adjust and control the morphology of pigment microcapsules,the effects of homogenization shear rate,agitation speed,dispersant TCP amount and pigment concentration on the particles size and size distribution of polymerization products were investigated.It was found that there was a critical agitation speed of 250 r·in^-1 for achieving a stable size and size distribution of dispersed phase during polymerization.TCP amount had a significant effect on the stability of micro-suspension system but a limited effect on particle size control.Homogenization shear rate played an obvious role in controlling particle size,while the effect of pigment concentration on particle size was not obvious.Thus a series of pigment microcapsules with controllable particle size,narrow distribution and high pigment content could be obtained.

Key words: pigment microcapsules, micro-suspension polymerization, particle size controlling

中图分类号:

TQ32517

戚栋明, 陈智杰, 赵晓丽, 徐杰, 申兴丛, 杨雷. 微悬浮法制备有机颜料微胶囊中的粒径调控[J]. 化工学报, 2013, 64(3): 1118-1123.

QI Dongming, CHEN Zhijie, ZHAO Xiaoli, XU Jie, SHEN Xingcong, YANG Lei. Particle size control of organic pigment microcapsules prepared via micro-suspension polymerization[J]. CIESC Journal, 2013, 64(3): 1118-1123.

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微悬浮法制备有机颜料微胶囊中的粒径调控

Particle size control of organic pigment microcapsules prepared via micro-suspension polymerization

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