CIESC Journal

• 化工学报 • 上一篇    下一篇

蔗渣浆制造黏液纤维的研究

岑翼南,赵斌,欧阳均   

  1. 中国科学院应用化学研究所 ,中国科学院应用化学研究所 ,中国科学院应用化学研究所
  • 出版日期:1957-12-25 发布日期:1957-12-25

STUDIES ON THE VISCOSE PROCESS OF BAGASSE PULP

I. N. TSEN, B. CHAD, C. OUYANG Institute of Applied Chemistry, Academia Sinica   

  • Online:1957-12-25 Published:1957-12-25

摘要: <正>在黏液纤维制造中,用蔗渣浆代替木浆作原料,常被人怀疑甚至否定其可能性,其主要根据为草类纤维的形态结构不同於木材纤维,而以天然纤维的形态结构作为对原料适合与否的判断标准。我们认为:黏液丝浆的良好制备条件均应最大限度地破坏了天然纤维的形态结构,主要是细胞壁的组织。後者的存在影响丝光化与黄酸化的反应

Abstract: The behavier of a prehydrolysis caustic bagasse pulp in the viscose process was studied in comparison with a spruce sufite pulp. The degree of swelling in different concentrations of alkali solutions, the changes of carboxyl and aldehyde group contents and viscosity of the regenerated cellulose under various ageing conditions of alkali cellulose, the changes of solubility and degree of esterification of xanthate with different amounts of CS2 used during xanthation and the spinning with viscose method were compared. It was found that both pulps had a maximum degree of swelling in alkli solution at a concentration of 10-11 % NaOH. At the same concentration, the degree of swelling of bagasse pulp was greater than that of spruce pulp. With the increase of ageing temperature and time the carboxyl group content of cellucose increased, the viscosity decreased, but no much change in the aldehyde group content was observed. At the same condition of ageing, the oxidation and degradation of bagasse cellulose was faster. No much difference between the two pulps was found in the changes of solubility and degree of esterification of xanthate at xanthation with various amounts of CS2. The tensile strength of viscose filament from bagasse was 2.23 g/d (dry), 1.68 g/d (wet). This experiment confirmed the applicability of bagasse for the preparation of staple fiber.