CIESC Journal

• 化工学报 • 上一篇    下一篇

铂重整制取芳香烃及提高汽油辛烷值

吴惠锦,宋瑞雪,陈春英,林正仙   

  1. 石油工业部石油科学研究院 ,石油工业部石油科学研究院 ,石油工业部石油科学研究院 ,石油工业部石油科学研究院
  • 出版日期:1959-06-25 发布日期:1959-06-25

PLATFORMING OF STRAIGHT-RUN NAPHTHAS FOR AROMATICS AND OCTANE IMPROVEMENT

Wu WHEI-CHEN SOONG REI-SHUEH CHEN CHUEN-YING and LIN CHENG-SEN (The Research Institute of Petroleum Science, Ministry of Petroleum Industry)   

  • Online:1959-06-25 Published:1959-06-25

摘要: 在80毫升催化剂容量的恒温反应装置中进行了我国四种主要原油轻馏份(玉门、克拉玛依、川中直馏汽油60—130℃馏份及抚顺页岩焦油加氢油60—120℃馏份)铂重整制取芳香烃及玉门和克拉玛依直馏汽油80—180℃馏份提高辛烷值的试验。在制取芳香烃方面,获得了合理操作条件、物料平衡、产品分布等数据,四种原油轻馏份的铂重整生成油中芳香烃产率各为38.5%(重,玉门)、31.8%(重,克拉玛依)、46.6%(重,川中)和32.2%(重,抚顺),氢气产率为1.7—2.2%(重),液收率为90—94%(重)。在50毫升催化剂容量的活性装置中进行了2170小时寿命试验,芳香烃产率自38.8%下降至35.4%(体积);在提高汽油辛烷值方面,初步地研究了几种变数(温度、压力、空速)对产品液收率和辛烷值的影响,获得了合理操作条件,反应产品的液收率为90%(重)左右,脱丁烷产品的辛烷值可自原料油的44左右提高至72以上。(马达法,未加铅)。

Abstract: Straight-run naphthas of Yumen, Kramayi, Central Szechuan (60-130℃), and Fushuan hydrogenated shale oil (60-120℃) were platformed separately for aromatics in an isothermal reactorcontaining 80 ml. catalyst. The catalyst used in this study was developed at the Research Institute of Petroleum Science, Ministry of Petroleum Industry. Data are presented to show platforming conditions, material balance and product distributions. Aromatic yields on weight basis were 38.5% (Yumen), 31.8% (Kramayi), 46.6% (Central Szechuan) and 32.2% (Fushun) respectively. Byproduct hydrogen yield was 1.7-2.2% (weight basis), liquid yield was 90-94% (weight basis). During 2170 hours catalyst life test, the aromatic yield decreased from 38.8% to 35.4% 80-180℃ straight-run Yumen and Kramayi gasolines for octane improvement were preliminarily investigated. At a yield of 90% (weight basis), debutanized reformed gasoline had a clear octane number of 72 (motor method). The octane number of the feed stock was 44 (motor method).