CIESC Journal

• 化工学报 • 上一篇    下一篇

硬脂酸生产新工艺试验报告

  

  1. 轻工业部科学设计院食品研究所
  • 出版日期:1960-06-25 发布日期:1960-06-25

A STUDY OF NEW METHOD OF MANUFACTURING STEARINE

RESEARCH INSTITUTE OF FOOD, MLI.   

  • Online:1960-06-25 Published:1960-06-25

摘要: 硬脂酸旧的生产方法,手续繁琐,须经过多次压榨,否则成品中不饱和脂肪酸含量较多,质量就次。本研究系采用豆油或棉子油与桕油分别或混合进行极度氢化后水解,蒸馏即获得质量高的硬脂酸。以含水0.1%以下酸价0.5以下的精炼棉子油与桕油,用0.2—0.25%的镍催化剂,在表压5—10公斤,温度180—200℃情况下,在有良好搅拌的氢化罐内进行氢化,3小时以内即可达到极度氢化。继续裂解,6小时分解率可达到97%左右。成品的碘值在1以下。其中所含十八烷酸与十六烷酸的比例为45∶55或50∶50。因此完全适合化粧品工业所要求的规格。同时也避免了使用国内比较缺乏的牛羊油作为原料。

Abstract: The old method of manufacturing stearine is rather cumbersome. Pressing has to be repeated thrice, in order to get rid of the unsaturated acids, otherwise the quality will be inferior This new method is to use soy bean oil or cotton seed oil and Chinese vegetable tallow singly or together as raw materials. After hydrogenation, spliting and distillation, stearine of good quality is obtained. The raw materials must be refined first so that the water content is under 0.1%, the acid number is under 0.5. They are then hydrogenated in a hydrogenator with good stirring, with 0.2-0.25% Ni as catalyst under 5-10 kg/cm2 pressure at 180-200℃. In about three hours, they are almost completely hydrogenated. Spliting conversion reaches about 97% after 6 hrs. The iodine number of the products after distillation is under 1. The product consists of stearic acid and palmitic acid in the ratio of 45:55 or 50:50. It therefore conforms to the specifications as required by the cosmetics industry. This method does not have to use the comparatively Jcarce animal tallows as raw materials.