CIESC Journal

• 化工学报 •    下一篇

二水物真空冷却流程制造湿法磷酸的研究

吴佩芝,张萱三,單光渝   

  1. 上海化工研究院 ,上海化工研究院 ,上海化工研究院
  • 出版日期:1965-09-25 发布日期:1965-09-25

DIHYDRATE PROCESS FOR MANUFACTURING OF PHOSPHORIC ACID WITH VACUUM COOLING

Shanghai Research Institute of Chemical Industry WU PEI-CHU, CHANG SHOU-SHAN, SAN KONG-YU   

  • Online:1965-09-25 Published:1965-09-25

摘要: 以某地磷矿制造湿法磷酸的中间试验工厂的研究工作,包括两个部分。在分解系统中,五个萃取槽顺序排列,磷矿粉从第一槽中加入,硫酸与过滤系统来的淡磷酸混合后从第二槽中加入。反应料浆从最后一槽抽出,用泵送至真空蒸发器,除去大部分的热,冷却后的料浆回流至第一槽。回浆倍数为13~15。 在过滤系统中,采用了水平连续倾覆盘式过滤机,过滤面积为1.5米~2。过滤机由15只滤盘组成。这些滤盘是自动加料、滤渣两次逆流洗滌、而后翻转排渣,过滤中可溶性P_2O_5的回收率大于99%。过滤机最大生产能力为800公斤干渣/米~2·时,成品酸(第一次滤液)浓度为30~32%P_2O_5。

Abstract: The manufacture of phosphoric acid from phosphate rock by wet process has been studied. The pilot plant consists of two systems, digestion system(I) and filtration system (II) . In(I),five reaction tanks are arranged in series. The ground phosphate rock is fed into the first tank. Sulfuric acid mixed with weak phosphoric acid returned from (II) is fed into the second one. The digested slurry from the last tank is pumped to a vacuum flash cooler, where most of heat is removed. The cooled slurry flows back into the first tank with a circulating ratio of 13~15:1. In (II), a continuous horizontal tilting-pan type filter is used, which comprises 15 seperate filter pans having a total filtering area of 1.5 square meters. The pans can be filled automatically. The filter cake, which is subjected to two counter-current washes, can be unloaded by automatically overturning the pans. The recovery of soluble P2O5 from filtration is >99% . The maximum capacity of the filter is 800 kg. dry cake/M2-hr.. The acid produced (from the first filtrate) is 30~32%P2O5.