CIESC Journal

• 化工学报 • 上一篇    下一篇

减压柴油管式炉裂解制烯烃

蔡惠林,张在瑜,茅文星,王德良,施咸礽   

  1. 北京化工硏究院 ,北京化工硏究院 ,北京化工硏究院 ,北京化工硏究院 ,北京化工硏究院
  • 出版日期:1979-12-25 发布日期:1979-12-25

Olefins Manufacture from Vacuum Gas Oil in Tubular Furnace

Cai Hui-lin Zhang Zai-yu Mao Wen-xing Wang De-liang Shi Xian-reng Beijing Research Institute of Chemical Industry   

  • Online:1979-12-25 Published:1979-12-25

摘要: 中国某些产地的原油具有低硫、高石蜡烃和低芳烃含量的特性。用这类原油炼制所得的减压柴油馏分具有同样特征,因而预测将有良好的裂解性能。为此进行了工艺研究。 在处理量约为2公斤/时,温度和压力分布可以模拟的裂解装置中,进行了中国减压柴油动力学研究和裂解产品分布规律试验。根据模试结果;综合中试和部分工业数据,提出了减压柴油裂解反应速度常数方程的有关参数值,以及原料特性和工艺参数对裂解产品收率关联图及数学关联式。 在处理量为100公斤/时的中试裂解装置中进行产品分布试验和工艺过程有关技术研究,着重考察了炉管对流段、辐射段的运转情况、高压急冷锅炉的操作特性。 研究结果表明,在760℃中等裂解深度时,汽油比为0.75—1,停留时间0.4—0.5秒,烃分压0.8公斤/厘米~2,主要产品收率为:乙烯22.5—23%,丙烯16—17.5%,丁二烯4.7—5.2%,重质燃料油10—12%。该油品与国外中东轻柴油裂解所得产物收率相仿,是工业管式炉的一种好原料。

Abstract: Low sulfur, high paraffin content and low aromaticity are the characteristics of some Chinese crudes. The vacuum gas oil obtained from these crudes have similar properties and therefore excellent cracking performance is to be expected. The pyrolysis kinetics and product yield pattern of the vacuum gas oil have been studied in a bench scale unit having about 2 kg/h hydrocarbon throughput capacity, where the temperature and pressure are profile controlled. Based on the data from experiments on bench scale unit, pilot plant and commercial pyrolysis furnace, parameters of the reaction rate constant equation for vacuum gas oil cracking have been determined, and the curves and equations correlating the feedstock properties and operating conditions against main products yields have also been expressed. A semi-commercial pilot plant of about 100 kg/h hydrocarbon throughput capacity, is used to confirm the products yield pattern and study the process technology, particularly to observe the coking tendency of the pyrolysis coil and the operating performance of the transfer line exchanger quenching device. It is found that at medium severity, with steam to oil ratio 0.75-1.00, residence time 0.4-0.5 sec., hydrocarbon partial pressure 0.8 kg/cm2,the main products yields are as follows, ethylene 22.5-23.0%, propylene 16.0-17.5%,butadiene 4.7-5.2%, heavy fuel oil 10-12%. The yields are similar to those obtained from the Middle East atmospheric gas oil cracking. Thus it is proved that the Chinese vacuum gas oil is a competitive feedstock for the manufacture of lower olefins in tubular pyrolysis furnace.