CIESC Journal

• 化工学报 • 上一篇    下一篇

内循环式无梯度反应器的研究

李绍芬,高文新,廖晖   

  1. 天津大学化工系 ,天津大学化工系 ,天津大学化工系
  • 出版日期:1980-03-25 发布日期:1980-03-25

A Study of Internal Recycle Gradientless Reactor

Li Shao-fen Gao Wen-xin Liao Hui Department of Chemical Engineering, Tianjin University   

  • Online:1980-03-25 Published:1980-03-25

摘要: 设计了一种内循环式无梯度反应器,可用以进行气固相催化反应动力学的研究。反应器的结构简单。采用电磁搅拌器以克服旋转轴径向密封的困难。催化剂可静置于多孔板上,或放在转篮中与轴一起运动。催化剂的粒度从零点几毫米至工业粒度均可适用。经停留时间分布测定证明反应器内气体的流动状况属于理想混合。径向及轴向的温度差甚小。这种反应器可以在800℃以下的温度操作。 研究了不同的气体体积流量下停留时间分布和搅拌速率间的关系。为了达到完全混合状态,较高的气体流量要求较高的搅拌速率。此外,在不同的搅拌速率下,还测定了反应器出口反应物的浓度,当搅拌速率增加至某一定数值后,组成不再改变。

Abstract: An internal recycle gradientless reactor had been designed for studying gas/solid catalytic reaction kinetics. The construction of the reactor is simple. The electromagnetic stirrer was employed in order to overcome the difficulties of the radial sealing of the rotating shaft. The catalyst may be put on the perforated fixed plate or in the rotating basket moving with the shaft. It enables to accommodate catalyst size from a few tenth of a milimeter to commercial size. Residence time distribution measurements showed that the gas flow pattern was ideal mixing flow. The axial and radial temperature differences in the reactor were very small. The reactor may be operated up to 800(C). The relation between residence time distribution and the stirring speed for various gas volumetric rate was studied. In order to reach perfect mixing state, higher stirring speed were required for higher gas flow rate. The re-actant concentrations in reactor effluent were measured under various stirring speed. The compositions were unchanged after the stirring speed had been increased to a certain value.