CIESC Journal

• 化工学报 • 上一篇    下一篇

聚酯反应动力学的半经验公式

潘强余,张常群,何仁文   

  1. 北京化工学院 ,北京化工学院 ,北京化工学院
  • 出版日期:1980-03-25 发布日期:1980-03-25

A Semi-Empirical Equation for the Kinetics of Polyesterification

Pan Qiang-yu Zhang Chang-qen He Ren-wen Department of chemical Engineering, Beijing Institute of Chemical Technology   

  • Online:1980-03-25 Published:1980-03-25

摘要: 考虑了对苯二甲酸乙二酯(BHET)缩聚过程的主反应、逆反应及热裂解反应,得到一个动力学方程式。再对不同类型和不同工况的工业反应器的实测数据进行综合分析,从而经验地确定了动力学方程式中不易测定的乙二醇(EG)浓度与搅拌速度、熔体的比表面等的关联式。最后得到了聚合度(DP)随工艺条件(温度T、压力p、反应肘间τ)及反应器的结构参数(搅拌速度R、反应体系的比表面ε)变化的半经验公式这个公式能够概括前人提出的一些公式,并能解释已经发表的许多实验曲线,可以定性和半定量地解决缩聚反应器设计中的问题。

Abstract: With the consideration of all the reactions involved in the polyesterification of BHET (bis-β-hydroxyethyl terepliathalate) such as the primary forward polycondensation reaction, its reverse reaction and the cracking reaction, a kinetic equation was derived. As the concentration of ethylene glycol (EG) appeared as a term in the derived equation is difficult to determine, it was empirically correlated with the speed of stirring, R, the specific surface of the reacting system, etc. Finally a semiempirical equation correlating the average degree of polyesterification ( DP )with both the operating parameters (such as the temperature T, pressure p and the time of residence ) and the constructional parameters of the industrial reactors(such as R and ε)has been obtained as follows: