CIESC Journal

• 化工学报 •    下一篇

马丁-侯状态方程向液相发展

侯虞钧,张彬,唐宏青   

  1. 浙江大学 ,浙江大学 ,兰化公司设计院
  • 出版日期:1981-03-25 发布日期:1981-03-25

Extension of Martin-Hou Equation of State into Liquid Region

Y. C. Hou, Zhang Bin and Tong Hongqing Zhejiang University Design Institute of Lanzhou Chemical Co.   

  • Online:1981-03-25 Published:1981-03-25

摘要: 1955年发表的气体状态方程式经过改进后,其应用范围扩展到液相。在原方程中增加了一个常数,B_4,即: P=RT/(V-b)+(A_2+B_2T+C_2e~(-5.475Tr))/(V-b)~2+(A_3B_3T+C_3e~(-5.475Tr))+(A_4+B_4T)/(V-b)~4+(B_5T)/(V-b)~5并且使方程式满足一个条件,integral from n=V_1 to V_0(PdV)=P_0(V_0-V_1),就可以求出常数B_4的数值。 改进后的方程对一般物质,如二氧化碳、正丁烷、氩、甲烷及氮等,在对比温度Tr约从0.65到临界温度,计算的饱和液相的摩尔容积与文献数据比较,平均偏差不到5%。同时,气相的摩尔容积基本上保持原来的精确度(偏差在1%以内)。并且,不须要增加所需的数据。

Abstract: The range of application of the equation of state proposed by Martin and Hou for gases was extended into liquid region. The improvement was achieved by retaining the constant, B4, in the original equation, namely and imposing the condition, , on the equation. The constant, B4, was then evaluated for a given compound. The calculated values of the saturated liquid molar volumes for carbon dioxide, normal butane, argon, methane and nitrogen, were compared with the data reported, in the reduced temperature range from about 0.65 to 1.0. The average deviation was less than 5% in each case, without loss of accuracy in gaseous region. Furthermore, no additional data were required for evaluation of the constants of the improved equation.