CIESC Journal

• 化工学报 • 上一篇    下一篇

聚丙烯纺丝中纤维不均匀性的研究

范庆荣,赵得禄,徐端夫,钱人元   

  1. 中国科学院化学研究所 ,中国科学院化学研究所 ,中国科学院化学研究所 ,中国科学院化学研究所
  • 出版日期:1981-12-25 发布日期:1981-12-25

A Study on Non-Uniformity of Melt-Spun Polypropylene Fibers

Fan Qingrong, Zhao Delu, Xu Duanfu and Qian Renyuan Institute of Chemistry, Academia Sinica   

  • Online:1981-12-25 Published:1981-12-25

摘要: 本文研究了聚丙烯树脂、纺丝条件等对聚丙烯纺丝过程中纤维不均匀性的影响。试验证明仅仅从流变学的角度来研究聚丙烯纺丝过程中纤维直径的不均匀性是不够的,因为初生纤维的屈服应力和初始模量的不均匀性主要取决于其取向的不均匀性和结晶性的差别。因而为了改善初生纤维的牵伸性能、提高聚丙烯纤维的质量,应该以控制初生纤维的织构和织构的均匀性为原则来合理选择聚丙烯树脂原料和控制纺丝工艺条件。

Abstract: The effects of molecular weight, molecular weight distribution and melt-spinning conditions of polypropylene resins on texture formation and non-uniformity of polypropylene fibers were investigated. The as-spun polypropylene fibers produced by melt spinning frequently exhibit diameter fluctuations. Pure rheological studies on this phenomenon were made by many authors, but our experiment showed that the orientation fluctuation and the crystal-linity difference of as-spun fibers make trouble much more severe than fiber diameter fluctuation does in the polypropylene spinning process. Since the mechanical properties of fibers, such as yield stress and initial modulus, depend on the orientation and crystallinity of as-spun fibers, the stretchability of as-spun fiber becomes worse with increasing orientation fluctuation and cry-stallinity. That means flow-induced crystallization plays a predominant role in fiber uniformity of polypropylene spinning process. Therefore, in order to improve the streching behavior of the as-spun fibers and the quality of the product fibers, the texture together with its uniformity of the as-spun fibers should be controlled by a reasonable choise of polypropylene resin as well as spinning condition.