CIESC Journal

• Original Article •    下一篇

EXTENSION OF MARTIN-HOU EQUATION OF STATE INTO LIQUID REGION

侯虞钧1; 张彬1; 唐宏青2   

  1. 1 Zhejiang University

    2 Design Institute of Lanzhou Chemical Co.

  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1983-12-28 发布日期:1983-12-28
  • 通讯作者: 侯虞钧

EXTENSION OF MARTIN-HOU EQUATION OF STATE INTO LIQUID REGION

HOU Yujun1; ZHANG Bin1; TANG Hongqing2   

  1. 1 Zhejiang University

    2 Design Institute of Lanzhou Chemical Co.
  • Received:1900-01-01 Revised:1900-01-01 Online:1983-12-28 Published:1983-12-28
  • Contact: HOU Yujun

摘要: The range of application of the equation of state proposed by Martin and Hou for gases was extendedinto liquid region.The improvement was achieved by retaining the constant,B_,in the original equation,namelyP=(RT)/(V-b)+(A_2+B_2T+C_2e~(-5.475))T_r+(A_3+B_3T+C_3e~(-5·475))T_r+(A_4+B_4T)/(V-b)~4+(B_5T/(V-B)~5)and imposing the condition,PdV=P_0(V_v-V_l),on the equation.The constant,B_4,was then evaluatedfor a given compound.The calculated values of the saturated liquid molar volumes for carbon dioxide,normal butane,argon,methane and nitrogen,were compared with the data reported,in the reduced temperature rangefrom about 0.65 to 1.0.The average deviation was less than 5% in each case,without loss of accuracyin gaseous region.Furthermore,no additional data were required for evaluation of the constants of theimproved equation.

Abstract: The range of application of the equation of state proposed by Martin and Hou for gases was extendedinto liquid region.The improvement was achieved by retaining the constant,B_,in the original equation,namelyP=(RT)/(V-b)+(A_2+B_2T+C_2e~(-5.475))T_r+(A_3+B_3T+C_3e~(-5·475))T_r+(A_4+B_4T)/(V-b)~4+(B_5T/(V-B)~5)and imposing the condition,PdV=P_0(V_v-V_l),on the equation.The constant,B_4,was then evaluatedfor a given compound.The calculated values of the saturated liquid molar volumes for carbon dioxide,normal butane,argon,methane and nitrogen,were compared with the data reported,in the reduced temperature rangefrom about 0.65 to 1.0.The average deviation was less than 5% in each case,without loss of accuracyin gaseous region.Furthermore,no additional data were required for evaluation of the constants of theimproved equation.