CIESC Journal

• Original Article • 上一篇    

A Mathematical Model for Emulsion Polymerization

曹同玉1; A. J. MERRY2; M. P. WILSON3   

  1. 1 Department of Chemical Engineering, Tianjin University

    2 Patterson Candy, International Ltd., Whitchurch, Hants, U.K.

    3 Department of Chemical Engineering, University of Aston, Birmingham, U.K.

  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1983-12-28 发布日期:1983-12-28
  • 通讯作者: 曹同玉

A Mathematical Model for Emulsion Polymerization

CAO Tongyu1; A. J. MERRY2; M. P. WILSON3   

  1. 1 Department of Chemical Engineering, Tianjin University

    2 Patterson Candy, International Ltd., Whitchurch, Hants, U.K.

    3 Department of Chemical Engineering, University of Aston, Birmingham, U.K.

  • Received:1900-01-01 Revised:1900-01-01 Online:1983-12-28 Published:1983-12-28
  • Contact: CAO Tongyu

摘要: Experimental studies of emulsion and suspensoon polymerization of styrene at 50~C are reported.Amathematical model for a batch emulsion polymerization in a unbaffled reactor with stirrer is proposed.This model allows for not only the effect of adsorption of the emulsifier onto the monomer droplets butalso the gel-effect.Data from the suspension polymerization tests are used to determine the relationshipbetween K_t and X_p Conclusion of these data in the model provided a good prediction of the number andsize of the latex particles and the conversion rate over most of the conversion range.

Abstract: Experimental studies of emulsion and suspensoon polymerization of styrene at 50~C are reported.Amathematical model for a batch emulsion polymerization in a unbaffled reactor with stirrer is proposed.This model allows for not only the effect of adsorption of the emulsifier onto the monomer droplets butalso the gel-effect.Data from the suspension polymerization tests are used to determine the relationshipbetween K_t and X_p Conclusion of these data in the model provided a good prediction of the number andsize of the latex particles and the conversion rate over most of the conversion range.