CIESC Journal

• Original Article •    下一篇

DETERMINATION OF EQUILIBRIUM VAPOR COMPOSITION FROM THE VAPOR PRESSURE OR BOILING POINT OF THE SOLUTION BY DIRECT METHOD

胡英; 英徐根   

  1. East China Institute of Chemical Technology
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1984-12-28 发布日期:1984-12-28
  • 通讯作者: 胡英

DETERMINATION OF EQUILIBRIUM VAPOR COMPOSITION FROM THE VAPOR PRESSURE OR BOILING POINT OF THE SOLUTION BY DIRECT METHOD

HU Ying; YING Xugen   

  1. East China Institute of Chemical Technology
  • Received:1900-01-01 Revised:1900-01-01 Online:1984-12-28 Published:1984-12-28
  • Contact: HU Ying

摘要: A direct method for evaluating equilibrium vapor compositions from measurements of the vapor pres-sure or boiling point of the solutions is presented.The basic differential equations are derived from Gibbs-Duhem equation and can be solved easily by iterative method.This method can be successfully used forbinary systems,and in principle can also be applied to multicomponent systems.Several examples ofbinaries and ternaries are presented for demonstration.Calculated results are in good agreement with ex-perimental data.

Abstract: A direct method for evaluating equilibrium vapor compositions from measurements of the vapor pres-sure or boiling point of the solutions is presented.The basic differential equations are derived from Gibbs-Duhem equation and can be solved easily by iterative method.This method can be successfully used forbinary systems,and in principle can also be applied to multicomponent systems.Several examples ofbinaries and ternaries are presented for demonstration.Calculated results are in good agreement with ex-perimental data.