CIESC Journal

• 化工学报 • 上一篇    下一篇

不同的BET型混合气体吸附公式的应用和比较

顾惕人   

  1. 北京大学化学系
  • 出版日期:1984-03-25 发布日期:1984-03-25

The Comparison of Different BET-Type Mixed Adsorption Equations with Some Experimental Results

Gu Tiren Department of Chemistry, Beijing University   

  • Online:1984-03-25 Published:1984-03-25

摘要: 本文将Bussey的BET型混合吸附公式应用于30℃时环己烷-乙醇、苯一乙醇和环已烷-苯的混合蒸气在Cab-O-Sil上的吸附,以及—185.6℃时氧-氮和氧-氩混台气体在铬胶上的吸附,并与Hill的和作者的BET型混合吸附公式的结果作了比较.由于Hill的公式太复杂,而其结果又与Bussey公式的差别不大,故从应用的角度看,不宜推荐.Bussey的和作者的公式因只含单纯气体吸附的BET参数,故应用方便;但自现有的实验结果,尚不能判断两者的优劣.

Abstract: The Busseys BET-type mixed adsorption equations have been applied to adsorption from mixed vapors of cyclohexane-ethanol, benzene-ethanol, and benzene-cyclohexane on Cab-O-Sil at 30℃, and to adsorption from oxygen-nitrogen and oxygen-argon on chromic oxide gel at - 185.6℃. The results are compared with experimental data, and also with authors and Hills BET-type mixed adsorption equations. Since Hills equation is much more complex than Busseys and authors equations, and its predictions are not much different from those of Busseys equation, it is not recommended for application. On the other hand, both the Bussey s and authors equations contain exclusively the parameters of BET equations for single vapors; therefore, they are easy to apply. For some systems the predictions of authors equation are better than those of Busseys equation, while for other systems the reverse is true. Therefore, from the present results, no conclusion can be reached about which is superior.