CIESC Journal

• 化工学报 •    下一篇

论固体表面的单分子与多分子吸附

李佐虎   

  1. 中国科学院化工冶金研究所
  • 出版日期:1985-06-25 发布日期:1985-06-25

Study on Mono-and Multimolecular Adsorption on Solid Surfaces

Li Zuohu (Institute of Chemical Metallurgy, Academia Sinica)   

  • Online:1985-06-25 Published:1985-06-25

摘要: 本文在前文提出的固体表面物理吸附模型基础上,主要针对多分子吸附进行探讨.采用de Boer提出的诱导极化概念及作者在模型中引入的随机微观吸附态概念,推导出三组新的多分子吸附等温式,可以很好地定量描述BrunauerⅠ、Ⅱ、Ⅲ类实验吸附等温线. B.E.T.公式只是其中极特殊的情况.

Abstract: The theoretical model for mono-and multimolecular adsorption on solid surfaces proposed by the author in the previous paper[1] is further studied. By applying the concept of induced polarization ?taking place in the next layer of molecules as suggested by de Boer, and the concept of micro -adsorption states introduced into the model by the author, three groups of multimolecular adsorption isotherm equations are derived, in which the B. E. T. (Brunauer-Emmett-Teller)equation is only a rare special case, and the Langmuir, Freundlich, and Temkin isotherms are transformed under certain conditions as shown in the previous paper. Those equations can be used to describe the different types of physical adsorption isotherms classified by Brunauer. The physical picture of multimolecular adsorption can be considered to involve an uniform liquid membrane with the thickness of a few molecules.