CIESC Journal

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STUDIES ON ULTRASONIC DEGRADATION AND BLOCK COPOLYMERIZATION OF POLYACRYLAMIDE AND POLY(ETHYLENE OXIDE)

胡星琪; 徐僖   

  1. Polymer Research Institute, Chengdu University of Science and Technology
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1985-12-28 发布日期:1985-12-28
  • 通讯作者: 胡星琪

STUDIES ON ULTRASONIC DEGRADATION AND BLOCK COPOLYMERIZATION OF POLYACRYLAMIDE AND POLY(ETHYLENE OXIDE)

HU Xingqi; XU Xi   

  1. Polymer Research Institute, Chengdu University of Science and Technology
  • Received:1900-01-01 Revised:1900-01-01 Online:1985-12-28 Published:1985-12-28
  • Contact: HU Xingqi

摘要: The kinetics of ultrasonic degradation of aqueous solution of polyacrylamide(PAM)and poly(ethyleneoxide)(PEO)as well as ultrasonic block copolymerization of aqueous solution of the mixture of PAM/PEOwere studied respectively.The degradation reaction of PEO follows a linear relationship between(P_1-P_∞)~(-1)and irradiation time,while that of PAM follows a linear relationship between(P_1-P_∞)~(-1/2)and irradiation time.The structure of the copolymer was identified by IR,NMR and DTA,and the copolymer prepared is a blockone.The copolymer formed by irradiating 1% aqueous solution of PEO/PAM mixture(1:1)for a period of40min.at 18.2 kHz with a sonic intensity corresponding to 2.OA input current on the reversed main circuitamounts to 61.8%.

Abstract: The kinetics of ultrasonic degradation of aqueous solution of polyacrylamide(PAM)and poly(ethyleneoxide)(PEO)as well as ultrasonic block copolymerization of aqueous solution of the mixture of PAM/PEOwere studied respectively.The degradation reaction of PEO follows a linear relationship between(P_1-P_∞)~(-1)and irradiation time,while that of PAM follows a linear relationship between(P_1-P_∞)~(-1/2)and irradiation time.The structure of the copolymer was identified by IR,NMR and DTA,and the copolymer prepared is a blockone.The copolymer formed by irradiating 1% aqueous solution of PEO/PAM mixture(1:1)for a period of40min.at 18.2 kHz with a sonic intensity corresponding to 2.OA input current on the reversed main circuitamounts to 61.8%.