CIESC Journal

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AN ENGINEERING MODEL FOR MULTICOMPONENT REVERSIBLE REACTION NETWORK

朱开宏; 陈敏恒; 袁渭康   

  1. East China Institute of Chemical Technology
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1985-12-28 发布日期:1985-12-28
  • 通讯作者: 朱开宏

AN ENGINEERING MODEL FOR MULTICOMPONENT REVERSIBLE REACTION NETWORK

ZHU Kaihong; CHEN Minheng; YUAN Weikang   

  1. East China Institute of Chemical Technology
  • Received:1900-01-01 Revised:1900-01-01 Online:1985-12-28 Published:1985-12-28
  • Contact: ZHU Kaihong

摘要: The treatment of a multicomponent reversible reaction network is extremely complicated because largenumber of rate constants must be precisely determined and because the calculation based on these rateconstants is tedious.In order to reduce the degrees of freedom of the process,the authors propose a methodin which the reactor and the separator are regarded as a whole.Based on this approach,an N-componentreversible reaction system can be dealt with as a two—component system.Consequently,a simple and ac-cessible way of the apparent rate determination is suggested.For fiist-order reactions,an explicit,simplifiedexpression has been derived for both lumped and distributed parameter reaction systems.

Abstract: The treatment of a multicomponent reversible reaction network is extremely complicated because largenumber of rate constants must be precisely determined and because the calculation based on these rateconstants is tedious.In order to reduce the degrees of freedom of the process,the authors propose a methodin which the reactor and the separator are regarded as a whole.Based on this approach,an N-componentreversible reaction system can be dealt with as a two—component system.Consequently,a simple and ac-cessible way of the apparent rate determination is suggested.For fiist-order reactions,an explicit,simplifiedexpression has been derived for both lumped and distributed parameter reaction systems.