CIESC Journal

• 化工学报 • 上一篇    下一篇

多孔催化剂有效因子的近似分析解(Ⅱ)近似分析解与数值解的比较

杨进,李绍芬   

  1. 天津大学化学工程系 ,天津大学化学工程系
  • 出版日期:1987-03-25 发布日期:1987-03-25

Approximate Analytical Solutions of EffectivenessFactor for Porous Catalysts (Ⅱ) Comparison between Analytical and Numerical Solutions

Yang Jin and Li Shaofen (Department of Chemical Engineering, Tianjin University)   

  • Online:1987-03-25 Published:1987-03-25

摘要: 根据本文第Ⅰ部分所提出的多孔催化剂有效因子近似计算式,针对不同形式的幂函数型动力学方程和双曲型动力学方程,计算了等温下Thiele模数不同时非一级反应的有效因子,并且用数值方法求出相应条件下的有效因子以作比较.大量的计算结果证明所提出的近似计算式较之文献上已有的近似式,不但精度高,而且适用范围广.同时近似式中参数估值简便,克服了以往研究者所提出的式子中这方面所存在的困难.

Abstract: According to the approximate analytical expression for effectiveness factorpreviously proposed by the authors, a great deal of calculations are made with power law type kinetic expressions and Langmuir-Hinshelwood kinetic expressions for three onedimensional catalyst pellets. The results show that our approximate solutions agree fairly well with the exact values obtained by numerical method in all circumstances investigated. The comparison with other approximate expressions in literature is made. As our expression is based on the analysis of the characteristics of the reaction system, the exactness is higher, the calculation is much easier, and above all, its scope of application is wider.