CIESC Journal

• 化工学报 • 上一篇    下一篇

氯化聚醚/氯醇橡胶多相共混体系熔体流变行为的研究

陆立明,李克斌,李世瑨   

  1. 华东化工学院 ,华东化工学院 ,华东化工学院
  • 出版日期:1987-12-25 发布日期:1987-12-25

The Melt Rheology of Chloro-Polyether and Polyepichlorohydrin Blends

Lu Liming, Li Kebing and Li Shijin (East China Institute of Chemical Technology)   

  • Online:1987-12-25 Published:1987-12-25

摘要: 本文研究了氯化聚醚/氯醇橡胶偶联共混物和非偶联共混物的流变性能,证实了不同配比的共混物熔体具有假塑性流体的流动行为,并在流变曲线的温度迭加和组成迭加基础上,建立了流变模型.

Abstract: The molten rheological properties of chloro-polyether and polyepichlo-rohydrin blends with a coupling agent and without coupling agents, were studied. It was found that coupling agents affect the pseudoplastic behayior of the blend melts. Shear stress-shear rate data of the blends at different temperatures constitute "master curves" at constant blending composition, when plotted as τ vs aTγ, and τ-γ data of the blends within a certain range of composition also constitute "master curves", when plotted as τ vs aTaφγ. A rheological equation which describes the relationship between viscosity and shear stress of the blends was established.