CIESC Journal

• 化工学报 • 上一篇    下一篇

动态法进行等温和等压汽液平衡的测定和控制研究

周星风,倪良,李浩然,兰贵全,韩世钧   

  1. 浙江大学化学系,浙江大学化学系,浙江大学化学系,浙江大学化学系,浙江大学化学系 杭州 ,杭州 ,杭州 ,杭州 ,杭州
  • 出版日期:1990-06-25 发布日期:1990-06-25

Determination and Control in Isothermal and Isobaric VLE Data Measurement by Dynamic Method

Zhou Xingfeng, Ni Liang, Li Haoran, Lan Guiquan and Han Shijun (Department of Chemistry, Zhejiang University, Hangzhou)   

  • Online:1990-06-25 Published:1990-06-25

摘要: 本文提出了用沸点控制来实现汽液平衡(VLE)测定中的等温或等压条件以及用沸点测定代替总压测定的基本原理,并建立了相应的仪器装置.实验表明,该测控装置在常、减压范围内的沸点控制精度和压力控制精度分别为±0.002℃和±0.003kPa.本文用此套自控装置并结合新型VLE测定仪,成功地测定了甲醇(1)-1,2二氯乙烷(2)在50.00℃和60.00℃下的等温VLE数据,并通过了逐点热力学一致性检验.实验表明,该套测控装置原理可靠,测定过程简便快速.

Abstract: An automatic boiling temperature control system for the measurement of both isothermal and isobaric vapor liquid equilibrium data.(T-P-x-y)by dynamic method is presented in this paper, along with the principle of temperature control and total pressure measurement. The absolute pressure control in isobaric VLE measurement can reach the precision of ± 0.02mmHg, and in isothermal VLE data measurement, the precision of the constant temperature control is within ± 0.002℃. The total pressure P is determined by using an ebul-liometer to measure the boiling point of pure water which is then converted to the total pressure. The schematic diagram of the system and the experimental procedure are given in detail. Using this automatic control system, isothermal VLE data of methanol (1)-1,2-dichloroethane (2) at 50.00℃ and 60.00℃ were measured, and both of the data sets passed the point-to-point thermodynamic consistency test. The system has the advantages of accuracy, simplicity and rapidity in isothermal VLE data measurement, and in general, a data point can be determined in about 5 to 10 minutes.