CIESC Journal

• 化工学报 • 上一篇    下一篇

流化床电化学反应器研究——(Ⅱ)导电机理及电位波动特性的实验研究

孙启文,朱英,朱炳辰   

  1. 华东化工学院,华东化工学院,华东化工学院 上海 ,上海 ,上海
  • 出版日期:1991-10-25 发布日期:1991-10-25

Study on The Fluidized Bed Electrochemical Reactor(Ⅱ) Conduction Mechanism and VoltageFluctuation Characteristics

Sun Qiwen, Zhu Ying and Zhu Bingchen (East China, University of Chemical Technology, Shanghai)   

  • Online:1991-10-25 Published:1991-10-25

摘要: 以电沉积金属银为实验体系,对流化床电化学反应器的电位波动特性进行了实验研究,考察了床层膨胀率、外加电压、流化状态等因素对电位波动的影响,并验证了本文(I)所提出的导电机理.

Abstract: In this paper, the voltage fluctuation characteristics are experimentally studied for a silver deposition system. At the same time, the influences on voltage fluctuation of the degree of expansion of fluidized bed, of the voltage difference between collector and counter, and of the fluidization state are investigated. The conduction mechanism proposed in Part( I ) is corroborated experimentally.The experimental results show that there are two manners for the particle and electrolyte voltage fluctuations, one of high frequency but low amplitude and the other of low frequency but high amplitude. When slugging or channeling appears, the particle voltage and the electrolyte voltage fluctuate irregularly while the overvoltage has essentially no irregular fluctuation. The influence of the voltage difference between collector and counter on the voltage fluctuations is rather pronounced. When the voltage difference is lower than about 1V for the reactor used there are essentially not low frequency, high amplitude voltage fluctuations. When the voltage difference is greater than about 1V, the low frequency, high amplitude voltage fluctuations for both the particle and electrolyte become more and more remarkable.