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孙启文,房鼎业,朱炳辰
Sun Qiwen, Fang Dingye and Zhu Bingchen (East China University of Chemical Technology, Shanghai 200237)By taking hydrogenations of CO and CO2 as key reactions and using orthogonal collocation method, the effectiveness factors were calculated for these two parallel reactions over cylindrical Cu-based methanol synthesis catalyst C301 according to a two-dimensional model. A comparison of calculated values with those of experiment showed the orthogonal collocation to be an effective and accurate mothod to calculate the effectiveness factors for parallel reactions.
摘要: 以一氧化碳和二氧化碳平行加氢反应作为铜基催化剂上甲醇含成的关键反应,按二维模型计算了圆柱状C301铜基催化剂上这两个反应的效率因子.将效率因子的模型计算值与实验测定值进行比较,表明正交配置法中计算平行反应效率因子的有效、准确的方法.