丁炔二醇加氢制1,4-丁二醇反应动力学研究

CIESC Journal

丁炔二醇加氢制1,4-丁二醇反应动力学研究

华萱,王承学

吉林工学院化工系,吉林工学院化工系长春130012 ,长春130012

出版日期:1992-02-25 发布日期:1992-02-25

Kinetics of Hydrogenation of Butynediol to1,4-Butanediol by Using Pd Catalyst ina Slurry Reactor

Hua Xuan and Wang Chengxue (Jilin Institute of Technology, Chemical Engineering Department, Changchun 130012)

Online:1992-02-25 Published:1992-02-25

摘要/Abstract

摘要： 用质量分数为0.41%Pd/γ-Al_2O_3催化剂,在间歇高压反应条件下进行丁炔二醇加氢制1,4-丁二醇的动力学研究.用动力学实验数据,对假设的机理速度方程进行筛选和鉴别.然后,对复杂的连串平行反应过程构成的微分方程组用Runge-Kutta法进行最优估值并求得各步反应的活化能.

华萱,王承学. 丁炔二醇加氢制1,4-丁二醇反应动力学研究 [J]. CIESC Journal.

Hua Xuan and Wang Chengxue (Jilin Institute of Technology, Chemical Engineering Department, Changchun 130012). Kinetics of Hydrogenation of Butynediol to1,4-Butanediol by Using Pd Catalyst ina Slurry Reactor[J]. .