甲醇合成铜基催化剂硫化氢中毒研究(Ⅰ)——硫化氢中毒本征失活动力学

CIESC Journal

甲醇合成铜基催化剂硫化氢中毒研究(Ⅰ)——硫化氢中毒本征失活动力学

应卫勇,房鼎业,姚佩芳,杜智美,朱炳辰

华东化工学院化工系,华东化工学院化工系,华东化工学院化工系,华东化工学院化工系,华东化工学院化工系上海200237 ,上海200237 ,上海200237 ,上海200237 ,上海200237

出版日期:1992-04-25 发布日期:1992-04-25

HYDROGEN SULFIDE POISONING OF METHANOL SYNTHESIS Cu-BASED CATALYST (I) INTRINSIC DEACTIVATION KINETICS

Ying Weiyong, Fang Dingye, Yao Peifang, Du Zhimei and Zhu Bingchen (Department of Chemical Engineering, East China Institute of Chemical Technology, Shanghai 200237)

Online:1992-04-25 Published:1992-04-25

摘要/Abstract

摘要： 研究了甲醇合成C207铜基催化剂硫化氢中毒本征失活动力学.研究表明,硫化氢分压增加,失活速率加快;温度升高,失活速率加快.本征失活速率方程为r_d=-da/dr=0.1474×10~(12)exp(-81128/R_gT)P_(H_2s~a)

应卫勇,房鼎业,姚佩芳,杜智美,朱炳辰. 甲醇合成铜基催化剂硫化氢中毒研究(Ⅰ)——硫化氢中毒本征失活动力学 [J]. CIESC Journal.

Ying Weiyong, Fang Dingye, Yao Peifang, Du Zhimei and Zhu Bingchen (Department of Chemical Engineering, East China Institute of Chemical Technology, Shanghai 200237). HYDROGEN SULFIDE POISONING OF METHANOL SYNTHESIS Cu-BASED CATALYST (I) INTRINSIC DEACTIVATION KINETICS[J]. .