CIESC Journal

• 化工学报 • 上一篇    下一篇

磷矿石熔融还原(Ⅱ)——磷酸盐还原动力学

郭占成,王大光,许志宏   

  1. 中国科学院化工冶金研究所!北京100080,中国科学院化工冶金研究所!北京100080,中国科学院化工冶金研究所!北京100080
  • 出版日期:1994-06-25 发布日期:1994-06-25

SMELTING REDUCTION OF PHOSPHORUS ORE (Ⅱ) KINETICS OF PHOSPHATE REDUCTION

Guo Zhancheng, Wang Daguang and Xu Zhihong(Institute of Chemical Metallurgy, Academia Sinica, Beijing 100080)   

  • Online:1994-06-25 Published:1994-06-25

摘要: 对固体石墨碳、Fe-P-C饱和熔体、CO气体还原熔融磷渣中磷酸盐的反应动力学进行了研究.固体石墨碳还原碱度B(CaO/SiO_2)为1.1、Al_2O_3含量约8.3%的熔融磷渣中磷酸盐的反应速度常数与温度的关系为k=1.1×10~3exp[-217360/(RT)];在一定温度下反应速度常数随渣碱度增大而增大.Fe-P-C饱和熔体还原熔融磷渣中磷酸盐的反应速度常数约比固体碳大1个数量级.CO气体还原熔融磷渣中磷酸盐的反应速度取决于CO气体流量,还原反应接近热力学平衡.

Abstract: The kinetics of the reduction of phosphate in molten slag by solid carbon,carbon in liquid iron saturated with carbon and phosphorus and CO gas was studied. Under the conditions of slag basicity CaO/SiO2 = l. 1,and A12O3 around 8. 3% ,the reaction rate constant of reduction of phosphate in molten slag by solid carbon was expressed byThe rate constant increased with the slag basicity. The rate constant of phosphate reduction by carbon in liquid iron saturated with carbon and phosphorus was about ten times larger than that by solid carbon under the same conditions. The reduction rate by CO gas only depended on the flow rate of CO gas. Its reduction reaction was close to thermodynamic equilibrium.

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